Influence of Diffusional Mobility of Polymerization System Components on the Rate Constants of Free Radical Polymerization

The rate constants of free radical polymerization are influenced by the diffusional mobility of the components of the polymerization system. A comprehensive study was undertaken to determine whether the existing theories of diffusion mobility can be used to quantitatively predict the rate constant c...

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Veröffentlicht in:International journal of polymeric materials 1996-09, Vol.34 (1), p.1-27
Hauptverfasser: Budtov, V. P., Podonosova, B. N.
Format: Artikel
Sprache:eng
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Zusammenfassung:The rate constants of free radical polymerization are influenced by the diffusional mobility of the components of the polymerization system. A comprehensive study was undertaken to determine whether the existing theories of diffusion mobility can be used to quantitatively predict the rate constant changes of the main chemical reactions of free radical polymerization.
ISSN:0091-4037
1563-535X
DOI:10.1080/00914039608031463