Catalytic Preparation and Characterization of C60Br24

In this paper the procedure for catalytical bromination of C 60 with elementary bromine with FeBr 3 as a catalyst is described. In this procedures only one reaction product - C 60 Br 24 is obtained. The twenty four bromine atoms are symmetrically distributed over the C 60 sphere, which was confirmed...

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Veröffentlicht in:	Fullerene science and technology 1998-01, Vol.6 (4), p.689-694
Hauptverfasser:	Djordjević, A., Vojínović-Miloradov, M., Petranović, N., Devečerski, A., Lazar, D., Ribar, B.
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalytic reactions Chemistry Exact sciences and technology General and physical chemistry Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
Online-Zugang:	Volltext
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Zusammenfassung:	In this paper the procedure for catalytical bromination of C 60 with elementary bromine with FeBr 3 as a catalyst is described. In this procedures only one reaction product - C 60 Br 24 is obtained. The twenty four bromine atoms are symmetrically distributed over the C 60 sphere, which was confirmed by thermogravimetric analysis. The yield of bromine derivative in this reaction is 98%.
ISSN:	1064-122X 1532-2343
DOI:	10.1080/10641229809350229