Activity coefficients and excess Gibbs energy of binary mixtures of N, N-dimethyl formamide with selected compounds at 95.5 kPa

Bubble point temperatures at 95.5 kPa, over the entire composition range, are measured for the binary mixtures of N, N-dimethyl formamide with: acetophenone, aniline, bromobenzene, chlorobenzene and N, N-dimethyl acetamide, employing a Swietoslawski-type ebulliometer. Liquid phase mole fraction vers...

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Veröffentlicht in:Fluid phase equilibria 2008-11, Vol.273 (1), p.52-58
Hauptverfasser: Vittal Prasad, T.E., Adi Sankara Reddy, A., Kailash, S., Prasad, D.H.L.
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Sprache:eng
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Zusammenfassung:Bubble point temperatures at 95.5 kPa, over the entire composition range, are measured for the binary mixtures of N, N-dimethyl formamide with: acetophenone, aniline, bromobenzene, chlorobenzene and N, N-dimethyl acetamide, employing a Swietoslawski-type ebulliometer. Liquid phase mole fraction versus bubble point temperature measurements are well represented by the Wilson model. Computed values of the activity coefficients and excess Gibbs energy are presented and discussed.
ISSN:0378-3812
1879-0224
DOI:10.1016/j.fluid.2008.07.018