A Ternary Metal−Organic Framework Built on Triangular Organic Spacers, Square and Tetrahedral Co2 Secondary Building Units

A Ternary Metal−Organic Framework Built on Triangular Organic Spacers, Square and Tetrahedral Co2 Secondary Building Units

A novel metal−organic framework (MOF) of Co12(BTC)8(DMF)6(µ2-H2O)2(µ-H2O)14⊃(solvent) (1⊃(solvents), BTC = 1,3,5-benzenetricarboxylate) prepared by the solvothermal reaction of CoCl2 and H3BTC in dimethylformamide presents another unique and unprecedented ternary MOF in which the triangular organic...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Crystal growth & design 2008-01, Vol.8 (1), p.176-178
Hauptverfasser: Luo, Feng, Che, Yun-xia, Zheng, Ji-min
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science
rheology
Exact sciences and technology
Materials science
Organic compounds
Other materials
Physics
Specific materials
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A novel metal−organic framework (MOF) of Co12(BTC)8(DMF)6(µ2-H2O)2(µ-H2O)14⊃(solvent) (1⊃(solvents), BTC = 1,3,5-benzenetricarboxylate) prepared by the solvothermal reaction of CoCl2 and H3BTC in dimethylformamide presents another unique and unprecedented ternary MOF in which the triangular organic spacers, square and tetrahedral secondary building units are alternately associated.
ISSN:1528-7483
1528-7505
DOI:10.1021/cg701081s