High-pressure study of low-compressibility Ta2N

Room temperature synchrotron x-ray diffraction experiments were performed on nanocrystal Ta2N in a diamond anvil cell to a pressure of 55.48 GPa. This nitride is a well-known kind of high-hardness material, and it is found to be highly incompressible. The structure is stable with no phase transition...

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Veröffentlicht in:Journal of physics. Condensed matter 2007-10, Vol.19 (42), p.425233-425233 (6)
Hauptverfasser: Lei, W W, Liu, D, Li, X F, Zhang, J, Zhou, Q, Hu, J Z, Cui, Q L, Zou, G T
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Sprache:eng
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Zusammenfassung:Room temperature synchrotron x-ray diffraction experiments were performed on nanocrystal Ta2N in a diamond anvil cell to a pressure of 55.48 GPa. This nitride is a well-known kind of high-hardness material, and it is found to be highly incompressible. The structure is stable with no phase transitions observed in this pressure range. The zero-pressure bulk modulus and its pressure derivative at ambient pressure are B0 = 360 +/- 3 GPa, B0' = 4, and in room conditions, the a and c parameters are 3.054 A, 4.996 A, respectively. The bulk modulus of Ta2N is greater than those of TaC, epsilon-TaN, Cr2N and MoN. The differences in bulk moduli might be due to the differences in structure and the cohesive energy among these phases.
ISSN:0953-8984
1361-648X
DOI:10.1088/0953-8984/19/42/425233