Experimental and predicted volumetric and refractive index properties of ternary mixtures of iodoethane with toluene and alcohols at temperature 298.15 K and pressure 101 kPa
Excess molar volumes V m E and change in refractive indices Δ mix n of the binary mixtures of (toluene + methanol), (toluene + ethanol), (toluene + 1-propanol), (toluene + iodoethane), (methanol + iodoethane), (ethanol + iodoethane), (1-propanol + iodoethane), and the ternary mixtures of (toluene +...
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Veröffentlicht in: | The Journal of chemical thermodynamics 2006-02, Vol.38 (2), p.201-208 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Excess molar volumes
V
m
E
and change in refractive indices Δ
mix
n of the binary mixtures of (toluene
+
methanol), (toluene
+
ethanol), (toluene
+
1-propanol), (toluene
+
iodoethane), (methanol
+
iodoethane), (ethanol
+
iodoethane), (1-propanol
+
iodoethane), and the ternary mixtures of (toluene
+
methanol
+
iodoethane), (toluene
+
ethanol
+
iodoethane), and (toluene
+
1-propanol
+
iodoethane) were measured with vibrating-tube densimeters and an Abbe-type refractometer at the temperature 298.15
K and the pressure 101
kPa. The experimental
V
m
E
and Δ
mix
n values of the ternary systems were predicted by empirical equations using binary solution data. |
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ISSN: | 0021-9614 1096-3626 |
DOI: | 10.1016/j.jct.2005.05.004 |