Di-μ-formato-1κ2O:2κ2O′-di-μ-pyridin-2-olato-1κO:2κN;1κN:2κO-bis[(2-pyridone-κO)copper(II)] acetonitrile 1.02-solvate
In the title compound, [Cu2(CHO2)2(C5H4NO)2(C5H5NO)2]·1.02CH3CN, the dimeric unit is centrosymmetric, with two bidentate pyridin‐2‐olate and two bidentate formate syn–syn bridges, and two apical 2‐pyridone ligands coordinated through the O atoms. The N atom from the apical 2‐pyridone ligand is a don...
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| Veröffentlicht in: | Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2005-12, Vol.61 (12), p.m526-m528 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
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| Online-Zugang: | Volltext |
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| Zusammenfassung: | In the title compound, [Cu2(CHO2)2(C5H4NO)2(C5H5NO)2]·1.02CH3CN, the dimeric unit is centrosymmetric, with two bidentate pyridin‐2‐olate and two bidentate formate syn–syn bridges, and two apical 2‐pyridone ligands coordinated through the O atoms. The N atom from the apical 2‐pyridone ligand is a donor of a hydrogen bond to the O atom of the bridging pyridinolate ligand of the same complex. The coordination polyhedron of the Cu atom is a distorted square pyramid. |
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| ISSN: | 0108-2701 1600-5759 |
| DOI: | 10.1107/S0108270105033871 |