Excess molar volumes and enthalpies for the binary systems propyl propanoate + o-xylene, m-xylene, and p-xylene at 298.15 K

This paper reports excess molar enthalpies, H m E, and excess molar volumes, V m E, of the binary systems {propyl propanoate + o-xylene}, {propyl propanoate + m-xylene} and {propyl propanoate + p-xylene} at the temperature 298.15 K and atmospheric pressure, over the whole composition range. V m E wa...

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Veröffentlicht in:Thermochimica acta 2004-10, Vol.420 (1), p.45-49
Hauptverfasser: Domı́nguez-Pérez, Montserrat, Jiménez de Llano, Julieta, Segade, Luisa, Cabeza, Oscar, Franjo, Carlos, Jiménez, Eulogio
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Sprache:eng
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Zusammenfassung:This paper reports excess molar enthalpies, H m E, and excess molar volumes, V m E, of the binary systems {propyl propanoate + o-xylene}, {propyl propanoate + m-xylene} and {propyl propanoate + p-xylene} at the temperature 298.15 K and atmospheric pressure, over the whole composition range. V m E was calculated from the experimental measurement of the corresponding densities, while H m E was measured directly. The excess magnitudes were correlated to a Redlich-Kister type equation. Finally, we will discuss the results of the three mixtures studied here and by comparison with other binary systems containing propyl propanoate and a benzene-based compound previously published.
ISSN:0040-6031
1872-762X
DOI:10.1016/j.tca.2003.11.056