catena-Poly­[[[di­aqua­bis(5-chloro­pyridinium-2-olato-κO)copper(II)]-μ-pyrazine-κ2N:N′] diperchlorate]

catena-Poly­[[[di­aqua­bis(5-chloro­pyridinium-2-olato-κO)copper(II)]-μ-pyrazine-κ2N:N′] diperchlorate]

In the title compound, [Cu(C5H4ClNO)2(C4H4N2)(H2O)2](ClO4)2, the Cu atom, which lies on an inversion centre, has an octahedral environment. The pyrazine ligand also lies about an inversion centre and links adjacent Cu atoms into a chain running along the b axis; perchlorate anions occupy the space b...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2002-04, Vol.58 (4), p.m270-m272
Hauptverfasser: Yuan, Ji-Xin, Hu, Mao-Lin, Cheng, Ya-Qian, Chen, Li-Chun, Ng, Seik Weng
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:In the title compound, [Cu(C5H4ClNO)2(C4H4N2)(H2O)2](ClO4)2, the Cu atom, which lies on an inversion centre, has an octahedral environment. The pyrazine ligand also lies about an inversion centre and links adjacent Cu atoms into a chain running along the b axis; perchlorate anions occupy the space between the chains, and the chains use the coordinated water mol­ecules to link to the anions, resulting in a hydrogen‐bonded ribbon structure. The donor 5‐chloro‐2‐hydroxy­pyridine ligand exists in the zwitterionic form, i.e. 5‐chloro­pyridinium‐2‐olate.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270102003852