Hexa-μ-chloro-μ4-oxo-tetrakis­[(4,5-di­hydro-2-methyl-1,2-thiazole-κN)copper(II)]

Hexa-μ-chloro-μ4-oxo-tetrakis­[(4,5-di­hydro-2-methyl-1,2-thiazole-κN)copper(II)]

The title compound, [Cu4Cl6O(C4H7NS)4], was obtained by the reaction of CuCl2·2H2O with 2‐methyl‐2‐thia­zoline in methanol. The complex has twofold crystallographic symmetry and contains a tetrahedron of four CuII atoms coordinating a central μ4‐O atom, with the six edges of the tetrahedron bridged...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Acta crystallographica. Section C, Crystal structure communications Crystal structure communications, 2002-01, Vol.58 (1), p.m29-m30
Hauptverfasser: Bolos, C. A., Christidis, P. C.
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: structure, mechanical and thermal properties
Exact sciences and technology
Inorganic compounds
Metal complexes
Physics
Structure of solids and liquids
crystallography
Structure of specific crystalline solids
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The title compound, [Cu4Cl6O(C4H7NS)4], was obtained by the reaction of CuCl2·2H2O with 2‐methyl‐2‐thia­zoline in methanol. The complex has twofold crystallographic symmetry and contains a tetrahedron of four CuII atoms coordinating a central μ4‐O atom, with the six edges of the tetrahedron bridged by Cl atoms. Distance ranges are Cu—O 1.917 (4)–1.920 (4) and Cu—Cl 2.370 (2)–2.445 (2) Å.
ISSN:0108-2701
1600-5759
DOI:10.1107/S0108270101016870