Universal Brønsted-Evans-Polanyi Relations for C-C, C-O, C-N, N-O, N-N, and O-O Dissociation Reactions

It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the dif...

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Veröffentlicht in:	Catalysis letters 2011-03, Vol.141 (3), p.370-373
Hauptverfasser:	Wang, Shengguang, Temel, Burcin, Shen, Juan, Jones, Glenn, Grabow, Lars C, Studt, Felix, Bligaard, Thomas, Abild-Pedersen, Frank, Christensen, Claus H, Nørskov, Jens K
Format:	Artikel
Sprache:	eng
Schlagworte:	BEP relations Bond breaking reactions CARBON COMPOUNDS Catalysis CHEM, COMP CHEMICAL BONDS CHEMICAL REACTION KINETICS Chemistry Chemistry and Materials Science Coupling reactions Cytokinins DENSITY FUNCTIONAL METHOD Density functional theory DISSOCIATION Exact sciences and technology General and physical chemistry Industrial Chemistry/Chemical Engineering INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Metal surfaces NITROGEN COMPOUNDS Organometallic Chemistry OXYGEN COMPOUNDS Physical Chemistry Scaling relations Stepped surfaces Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry TRANSITION ELEMENT COMPOUNDS Transition metals
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Zusammenfassung:	It is shown that for all the essential bond forming and bond breaking reactions on metal surfaces, the reactivity of the metal surface correlates linearly with the reaction energy in a single universal relation. Such correlations provide an easy way of establishing trends in reactivity among the different transition metals. Graphic Abstract [graphic removed]
ISSN:	1011-372X 1572-879X
DOI:	10.1007/s10562-010-0477-y