Surface-induced ferroelectric ice on Pt(111)

Surface-induced ferroelectric ice on Pt(111)

Optical sum-frequency vibrational spectroscopy and thermaldesorption are used to study ice films grown on Pt(111). The strongenhancement of OH stretch resonances with film thickness provides clearevidence for the presence of polar ordering of water molecules in thefilms. The ordering is induced by t...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Physical review letters 1997-10, Vol.80 (7)
Hauptverfasser: Su, X., Lianos, L., Shen, Y.R., Somorjai, G.A.
Format: Artikel
Sprache:eng
Schlagworte:
DEPOSITION
ICE
MATERIALS SCIENCE
ORDER PARAMETERS
PLATINUM
SURFACE PROPERTIES
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Optical sum-frequency vibrational spectroscopy and thermaldesorption are used to study ice films grown on Pt(111). The strongenhancement of OH stretch resonances with film thickness provides clearevidence for the presence of polar ordering of water molecules in thefilms. The ordering is induced by the polar anchoring of the first icemonolayer on platinum. It exhibits a characteristic behavior ofsurface-induced ordering phenomena with a decay length of 30monolayers.
ISSN:0031-9007
1079-7114