Direct Observation of Microscopic Inhomogeneities with Energy-Dispersive Diffraction of Synchrotron-Produced X-rays

Evidence of structural inhomogeneities in two high-transition-temperature superconductors, YBa$_2$Cu$_3$O$_{7-\delta}$ and Nd$_{2-x}$Ce$_x$CuO$_{4-y}$, is presented. When samples were illuminated by highly collimated x-rays produced on a synchrotron wiggler, small changes in the lattice were detected over a spatial scale of 10 micrometers. These changes are interpreted as evidence of variations in the oxygen content in one case and in the cerium content in the other; both affect the superconducting properties. The existence of such structural inhomogeneities brings into question whether exotic experimental results obtained from superconducting materials with high transition temperatures actually reflect intrinsic properties.