Structure, dynamics, and comparative stability of a mixed-ligand compound of tin(II)

Attempts to produce a copper(I) stannylene complex from the combination of Sn(N(SiMe{sub 3}){sub 2}){sub 2} with (Cu(O{sup t}Bu)){sub 4} were unsuccessful. Instead products resulting from ligand redistribution were produced. The reaction conditions and characterization studies of the reaction produc...

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Veröffentlicht in:	Inorganic chemistry 1989-10, Vol.28 (21), p.4051-4053
Hauptverfasser:	McGeary, Michael J, Folting, Kirsten, Caulton, Kenneth G
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties ALKANES CHEMICAL PREPARATION COMPLEXES Condensed matter: structure, mechanical and thermal properties COPPER COMPLEXES DATA Exact sciences and technology EXPERIMENTAL DATA HYDROCARBONS INFORMATION Inorganic compounds INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Metal complexes NITROGEN COMPLEXES NUMERICAL DATA ORGANIC COMPOUNDS OXYGEN COMPLEXES Physics SILICON COMPLEXES Structure of solids and liquids crystallography Structure of specific crystalline solids SYNTHESIS TIN COMPLEXES TRANSITION ELEMENT COMPLEXES
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Zusammenfassung:	Attempts to produce a copper(I) stannylene complex from the combination of Sn(N(SiMe{sub 3}){sub 2}){sub 2} with (Cu(O{sup t}Bu)){sub 4} were unsuccessful. Instead products resulting from ligand redistribution were produced. The reaction conditions and characterization studies of the reaction products are reported. 7 refs., 2 figs., 1 tab.
ISSN:	0020-1669 1520-510X
DOI:	10.1021/ic00320a024