Palladium-catalyzed oxidative carbonylation of ethylene and propylene by butyl nitrite and carbon monoxide

In the oxidative carbonylation of ethylene by carbon monoxide and butyl nitrite catalyzed by PdCl{sub 2}(PhCN){sub 2} in the presence of triphenylphosphine, the pentacoordinated tetravalent palladium complex PdCl{sub 2}(COOBu)NO(PPh{sub 3}) has been isolated and has proved to be an intermediate in t...

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Veröffentlicht in:	Organometallics 1990-01, Vol.9 (1), p.26-30
Hauptverfasser:	Brechot, Philippe, Chauvin, Yves, Commereuc, Dominique, Saussine, Lucien
Format:	Artikel
Sprache:	eng
Schlagworte:	ALKENES CARBON COMPOUNDS CARBON MONOXIDE CARBON OXIDES Carbonyl and nitrosyl metals CARBONYLATION CATALYSIS CHALCOGENIDES CHEMICAL REACTIONS Chemistry DATA DATA ANALYSIS ELEMENTS ETHYLENE Exact sciences and technology EXPERIMENTAL DATA HYDROCARBONS INFORMATION Inorganic chemistry and origins of life INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY METALS NITRITES NITROGEN COMPOUNDS NUMERICAL DATA ORGANIC COMPOUNDS OXIDES OXYGEN COMPOUNDS PALLADIUM PLATINUM METALS Preparations and properties PROPYLENE TRANSITION ELEMENTS 400200 > Inorganic, Organic, & Physical Chemistry
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Zusammenfassung:	In the oxidative carbonylation of ethylene by carbon monoxide and butyl nitrite catalyzed by PdCl{sub 2}(PhCN){sub 2} in the presence of triphenylphosphine, the pentacoordinated tetravalent palladium complex PdCl{sub 2}(COOBu)NO(PPh{sub 3}) has been isolated and has proved to be an intermediate in the catalytic cycle.
ISSN:	0276-7333 1520-6041
DOI:	10.1021/om00115a006