Observation of unexpected energy levels in molecular hydrogen and ortho-para energy transfer

We report the observation of eight unexpected energy levels close to but clearly different from H{sub 2} {ital B} {sup 1}{Sigma}{sub {ital u}}{sup +} levels. In transitions involving these levels vacuum-ultraviolet transitions terminating in p-H{sub 2} levels are observed subsequent to two-photon {i...

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Veröffentlicht in:Physical review letters 1990-06, Vol.64 (23), p.2763-2766
Hauptverfasser: CZARNETZKI, U, DÖBELE, H. F
Format: Artikel
Sprache:eng
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Zusammenfassung:We report the observation of eight unexpected energy levels close to but clearly different from H{sub 2} {ital B} {sup 1}{Sigma}{sub {ital u}}{sup +} levels. In transitions involving these levels vacuum-ultraviolet transitions terminating in p-H{sub 2} levels are observed subsequent to two-photon {ital Q}(1) excitation {ital X}{sup 1}{Sigma}{sub {ital g}}{sup +}({ital v}{prime}{prime}=0){r arrow}{ital EF} {sup 1}{Sigma}{sub {ital g}}{sup +}({ital v}{prime}=6) of o-H{sub 2}. Several findings indicate that these strange levels may be a manifestation of electronically excited H{sub 4}, which has been discussed in a number of theoretical contributions.
ISSN:0031-9007
1079-7114
DOI:10.1103/PhysRevLett.64.2763