Local thermodynamics of inhomogeneous fluids at equilibrium

Local thermodynamics of inhomogeneous fluids at equilibrium

Extensive thermodynamic parameters of inhomogeneous fluids in thermal equilibrium are expressed as integrals of corresponding locally defined quantities. In particular, the distinction between the grand canonical potential and the integrated mechanical pressure is discussed in terms of scale invaria...

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Veröffentlicht in:Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics Statistical physics, plasmas, fluids, and related interdisciplinary topics, 1995-01, Vol.51 (1), p.261-265
Hauptverfasser: Percus, JK, Pozhar, LA, Gubbins, KE
Format: Artikel
Sprache:eng
Schlagworte:
665000 > Physics of Condensed Matter-- (1992-)
CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
ENERGY
EQUILIBRIUM
FLUIDS
FREE ENERGY
FUNCTIONALS
FUNCTIONS
INVARIANCE PRINCIPLES
PHYSICAL PROPERTIES
SCALE INVARIANCE
THERMAL EQUILIBRIUM
THERMODYNAMIC PROPERTIES 661300 > Other Aspects of Physical Science-- (1992-)
THERMODYNAMICS
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Zusammenfassung:Extensive thermodynamic parameters of inhomogeneous fluids in thermal equilibrium are expressed as integrals of corresponding locally defined quantities. In particular, the distinction between the grand canonical potential and the integrated mechanical pressure is discussed in terms of scale invariance, and a similar analysis is made of the Helmholtz free energy.
ISSN:1063-651X
1095-3787
DOI:10.1103/PhysRevE.51.261