Dynamics of intervesicle transfer of dihexadecyl phosphate-bound viologens

Dynamics of intervesicle transfer of dihexadecyl phosphate-bound viologens

Transfer of an amphiphilic viologen dication between anionic vesicles was accelerated by a water-soluble anionic zinc porphyrin. On the basis of observed reactivity patterns, a novel mechanism involving viologen-zinc porphyrin ion pairing is proposed wherein the zinc porphyrin functions as a viologe...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Langmuir 1993-01, Vol.9 (1), p.16-18
Hauptverfasser: Patterson, Brian C, Hurst, James K
Format: Artikel
Sprache:eng
Schlagworte:
400201 - Chemical & Physicochemical Properties
ALKANES
ANIONS
AZINES
BIPYRIDINES
CARBOXYLIC ACIDS
CHARGED PARTICLES
CHEMICAL REACTIONS
Chemistry
Colloidal state and disperse state
ELEMENTS
Exact sciences and technology
General and physical chemistry
HETEROCYCLIC ACIDS
HETEROCYCLIC COMPOUNDS
HEXADECANE
HYDROCARBONS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
ION PAIRS
IONS
MASS TRANSFER
Membranes
METALS
MICELLAR SYSTEMS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PHOSPHATES
PHOSPHORUS COMPOUNDS
PORPHYRINS
PYRIDINES
ZINC
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Transfer of an amphiphilic viologen dication between anionic vesicles was accelerated by a water-soluble anionic zinc porphyrin. On the basis of observed reactivity patterns, a novel mechanism involving viologen-zinc porphyrin ion pairing is proposed wherein the zinc porphyrin functions as a viologen shuttle.
ISSN:0743-7463
1520-5827
DOI:10.1021/la00025a005