Reinvestigation of the electronic spectrum of the phenylnitrene radical

The origin band of the electronic transition long attributed to gaseous triplet phenylnitrene has been investigated by using a very high resolution pulsed laser to interrogate molecules cooled in a supersonic jet. The observed rotational and spin structure of this band is inconsistent with simple id...

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Veröffentlicht in:	Journal of physical chemistry (1952) 1990-05, Vol.94 (9), p.3387-3391
Hauptverfasser:	Cullin, David W, Yu, Lian, Williamson, James M, Platz, Matthew S, Miller, Terry A
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties Atomic and molecular physics DATA DATA ANALYSIS ELECTRONIC STRUCTURE Exact sciences and technology EXPERIMENTAL DATA INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Intensities and shapes of molecular spectral lines and bands MEASURING INSTRUMENTS MEASURING METHODS Molecular properties and interactions with photons NUMERICAL DATA ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS Physics RADICALS
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Beschreibung
Zusammenfassung:	The origin band of the electronic transition long attributed to gaseous triplet phenylnitrene has been investigated by using a very high resolution pulsed laser to interrogate molecules cooled in a supersonic jet. The observed rotational and spin structure of this band is inconsistent with simple ideas of triplet phenylnitrene's structure and spectra. Details of these inconsistencies are presented. A possible alternative carrier for the spectrum is presented.
ISSN:	0022-3654 1541-5740
DOI:	10.1021/j100372a010