Gas-phase inorganic chemistry: laser spectroscopy of calcium and strontium monoformamidates

The reaction products of calcium and strontium metal vapors with formamide were studied by using laser spectroscopic techniques. Three electronic transitions were observed for the resulting metal monoformamidates, MNHCOH. The formamidate ligand is probably bonding to the metal in a bidentate manner....

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Veröffentlicht in:	Journal of physical chemistry (1952) 1990-05, Vol.94 (9), p.3547-3549
Hauptverfasser:	Bopegedera, A. M. R. P, Fernando, W. T. M. L, Bernath, Peter F
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties ALKALINE EARTH METAL COMPOUNDS Atomic and molecular physics CALCIUM COMPOUNDS CARBOXYLIC ACID SALTS DATA DATA ANALYSIS Exact sciences and technology EXPERIMENTAL DATA Fluorescence and phosphorescence radiationless transitions, quenching (intersystem crossing, internal conversion) FORMATES INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY LASER SPECTROSCOPY MEASURING INSTRUMENTS MEASURING METHODS Molecular properties and interactions with photons NUMERICAL DATA Physics RADICALS SPECTROSCOPY STRONTIUM COMPOUNDS
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Beschreibung
Zusammenfassung:	The reaction products of calcium and strontium metal vapors with formamide were studied by using laser spectroscopic techniques. Three electronic transitions were observed for the resulting metal monoformamidates, MNHCOH. The formamidate ligand is probably bonding to the metal in a bidentate manner. The metal-ligand stretching vibrational frequencies were assigned from the low-resolution spectra.
ISSN:	0022-3654 1541-5740
DOI:	10.1021/j100372a035