Solubility of carbon monoxide in n-hexane between 293 and 473 K and CO pressures up to 200 bar

Solubility of carbon monoxide in n-hexane between 293 and 473 K and CO pressures up to 200 bar

The solubility of carbon monoxide, CO, in n-hexane was measured at 293, 323, 373, 423, and 473 K for CO partial pressures up to 200 bar. The enthalpy of solution was calculated between 293 and 473 K. Using the Krichevsky-Ilinskaya equation of state, the solubility of CO in n-hexane can be calculated...

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Veröffentlicht in:Journal of chemical and engineering data 1993-07, Vol.38 (3), p.437-440
Hauptverfasser: KOELLIKER, R, THIES, H
Format: Artikel
Sprache:eng
Schlagworte:
400201 - Chemical & Physicochemical Properties
ALKANES
CARBON COMPOUNDS
CARBON MONOXIDE
CARBON OXIDES
CARBONYLATION
CHALCOGENIDES
CHEMICAL REACTIONS
Chemistry
DATA
ENTHALPY
EQUATIONS
EQUATIONS OF STATE
Exact sciences and technology
EXPERIMENTAL DATA
General and physical chemistry
HEXANE
HIGH PRESSURE
HYDROCARBONS
INFORMATION
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
NUMERICAL DATA
ORGANIC COMPOUNDS
OXIDES
OXYGEN COMPOUNDS
PARTIAL PRESSURE
PHYSICAL PROPERTIES
SOLUBILITY
SOLUTION HEAT
Solutions
SOLVENT PROPERTIES
TEMPERATURE RANGE
TEMPERATURE RANGE 0273-0400 K
TEMPERATURE RANGE 0400-1000 K
THERMODYNAMIC PROPERTIES
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Beschreibung
Zusammenfassung:The solubility of carbon monoxide, CO, in n-hexane was measured at 293, 323, 373, 423, and 473 K for CO partial pressures up to 200 bar. The enthalpy of solution was calculated between 293 and 473 K. Using the Krichevsky-Ilinskaya equation of state, the solubility of CO in n-hexane can be calculated between 293 and 423 K for CO partial pressures up to 200 bar with an accuracy better than 5%.
ISSN:0021-9568
1520-5134
DOI:10.1021/je00011a029