Preparation of Zirconia Coatings by Hydrolysis of Zirconium Alkoxide with Hydrogen Peroxide

Preparation of Zirconia Coatings by Hydrolysis of Zirconium Alkoxide with Hydrogen Peroxide

Coatings of 8.8‐mol%‐yttria‐doped zirconia were fabricated using a transparent and spinnable sol prepared by hydrolysis of zirconium alkoxide with hydrogen peroxide and nitric acid. The sol gave a crack‐free coating film consisting of fine grains. The crystalline phase was cubic after heating at 100...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of the American Ceramic Society 1993-04, Vol.76 (4), p.1061-1064
Hauptverfasser: Sakurai, Chihiro, Fukui, Toshimi, Okuyama, Masahiko
Format: Artikel
Sprache:eng
Schlagworte:
360204 - Ceramics, Cermets, & Refractories- Physical Properties
400201 - Chemical & Physicochemical Properties
ACTIVATION ENERGY
ALKOXIDES
ALUMINIUM COMPOUNDS
ALUMINIUM OXIDES
Applied sciences
Building materials. Ceramics. Glasses
Ceramic industries
CHALCOGENIDES
Chemical industry and chemicals
CHEMICAL PREPARATION
CHEMICAL REACTIONS
COATINGS
DATA
DECOMPOSITION
DIAGRAMS
DOPED MATERIALS
ELECTRICAL PROPERTIES
ENERGY
Exact sciences and technology
EXPERIMENTAL DATA
FLOWSHEETS
GRAIN SIZE
HYDROGEN COMPOUNDS
HYDROGEN PEROXIDE
HYDROLYSIS
INFORMATION
INORGANIC ACIDS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
LYSIS
MATERIALS
MATERIALS SCIENCE
MICROSTRUCTURE
Miscellaneous
NITRIC ACID
NUMERICAL DATA
OPTICAL PROPERTIES
OXIDES
OXYGEN COMPOUNDS
PEROXIDES
PHYSICAL PROPERTIES
SIZE
SOLVOLYSIS
SYNTHESIS
Technical ceramics
TRANSITION ELEMENT COMPOUNDS
YTTRIUM COMPOUNDS
YTTRIUM OXIDES
ZIRCONIUM COMPOUNDS
ZIRCONIUM OXIDES
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Coatings of 8.8‐mol%‐yttria‐doped zirconia were fabricated using a transparent and spinnable sol prepared by hydrolysis of zirconium alkoxide with hydrogen peroxide and nitric acid. The sol gave a crack‐free coating film consisting of fine grains. The crystalline phase was cubic after heating at 1000° and 1200°C and cubic and tetragonal at 1350°C, with the coating being highly oriented in the (111) plane, especially at 1000°C. Activation energy of the coating films was higher than that of the bulk. Transmittance through a film thickness of about 0.3 μm on each side was 75%.
ISSN:0002-7820
1551-2916
DOI:10.1111/j.1151-2916.1993.tb05337.x