Is interstellar detection of higher members of the linear radicals CnCH and CnN feasible?
Rotational constants and dipole moments for linear-chain radicals CnCH and CnN are estimated using a combinatiaon of ab initio molecular orbital calculations and observed data on the starting members of the series. CnCH with n = 0-5 have been observed by radioastronomy in carbon-rich interstellar cl...
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Veröffentlicht in: | The Astrophysical journal 1991-03, Vol.369 (1), p.L13-L16 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | Rotational constants and dipole moments for linear-chain radicals CnCH and CnN are estimated using a combinatiaon of ab initio molecular orbital calculations and observed data on the starting members of the series. CnCH with n = 0-5 have been observed by radioastronomy in carbon-rich interstellar clouds; higher members of the series have 2Pi ground states with large dipole moments and are strong candidates for observation. CN and C3N have also been observed by radioastronomy; higher members of the series, with the possible exception of C5N, have 2Pi ground states with near-zero dipole moments making their interstellar detection hopeless under present observational conditions. C5N can be a strong candidate only if it has a 2Sigma ground state, and best computations so far indicate that this is not the case. |
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ISSN: | 0004-637X 1538-4357 |
DOI: | 10.1086/185948 |