Rhodium(II) complex with a highly reactive rhodium-rhodium bond: insertion of dioxygen and nitrosobenzene

The authors report the chemical preparation and some preliminary reaction chemistry of [Cp[sup *]Rh([mu]-Cl)][sub 2] (1) (Cp[sup *] = C[sub 5]Me[sub 5]), a Rh(II) dimer with a reactive Rh-Rh bond. While many Rh(II) complexes containing Rh-Rh bonds have been reported in the literature, including seve...

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Veröffentlicht in:	Journal of the American Chemical Society 1990-02, Vol.112 (5), p.2024-2026
Hauptverfasser:	Sharp, Paul R, Hoard, David W, Barnes, Charles L
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties AROMATICS CHEMICAL REACTIONS COMPLEXES ELEMENTS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MOLECULAR STRUCTURE NITROSO COMPOUNDS NONMETALS ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS ORGANOMETALLIC COMPOUNDS OXYGEN RHODIUM COMPLEXES TRANSITION ELEMENT COMPLEXES
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