Rhodium(II) complex with a highly reactive rhodium-rhodium bond: insertion of dioxygen and nitrosobenzene

Rhodium(II) complex with a highly reactive rhodium-rhodium bond: insertion of dioxygen and nitrosobenzene

The authors report the chemical preparation and some preliminary reaction chemistry of [Cp[sup *]Rh([mu]-Cl)][sub 2] (1) (Cp[sup *] = C[sub 5]Me[sub 5]), a Rh(II) dimer with a reactive Rh-Rh bond. While many Rh(II) complexes containing Rh-Rh bonds have been reported in the literature, including seve...

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Veröffentlicht in:Journal of the American Chemical Society 1990-02, Vol.112 (5), p.2024-2026
Hauptverfasser: Sharp, Paul R, Hoard, David W, Barnes, Charles L
Format: Artikel
Sprache:eng
Schlagworte:
400201 - Chemical & Physicochemical Properties
AROMATICS
CHEMICAL REACTIONS
COMPLEXES
ELEMENTS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MOLECULAR STRUCTURE
NITROSO COMPOUNDS
NONMETALS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
ORGANOMETALLIC COMPOUNDS
OXYGEN
RHODIUM COMPLEXES
TRANSITION ELEMENT COMPLEXES
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Zusammenfassung:The authors report the chemical preparation and some preliminary reaction chemistry of [Cp[sup *]Rh([mu]-Cl)][sub 2] (1) (Cp[sup *] = C[sub 5]Me[sub 5]), a Rh(II) dimer with a reactive Rh-Rh bond. While many Rh(II) complexes containing Rh-Rh bonds have been reported in the literature, including several analogues of 1, the high reactivity of the Rh-Rh bond in 1 is remarkable and has allowed this group to prepare several unusual products.
ISSN:0002-7863
1520-5126
DOI:10.1021/ja00161a071