Fiber-optic organic vapor sensor
The application of fibre-optic technology to the monitoring of volatile organic compounds in soil groundwater samples is described. Sensors and supporting portable instruments suitable for field applications were developed for continuous in-situ measurements. The sensor's operation depends on f...
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Veröffentlicht in: | Environmental science & technology 1991-07, Vol.25 (7), p.1301-1304 |
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creator | Barnard, Steven M Walt, David R |
description | The application of fibre-optic technology to the monitoring of volatile organic compounds in soil groundwater samples is described. Sensors and supporting portable instruments suitable for field applications were developed for continuous in-situ measurements. The sensor's operation depends on fluorescence modulation in the presence of volatile organic vapours. Polymer absorption of organic vapours results in a concomitant enhancement of fluorescence in an immobilized fluorophor. In-situ field tests conducted at a jet fuel contamination site showed a detection limit of 10 ppm and a response time of 2.5 minutes with 7.5 per cent signal change. |
doi_str_mv | 10.1021/es00019a012 |
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Sensors and supporting portable instruments suitable for field applications were developed for continuous in-situ measurements. The sensor's operation depends on fluorescence modulation in the presence of volatile organic vapours. Polymer absorption of organic vapours results in a concomitant enhancement of fluorescence in an immobilized fluorophor. In-situ field tests conducted at a jet fuel contamination site showed a detection limit of 10 ppm and a response time of 2.5 minutes with 7.5 per cent signal change.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es00019a012</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>02 PETROLEUM ; 020900 - Petroleum- Environmental Aspects ; 440800 - Miscellaneous Instrumentation- (1990-) ; 540220 - Environment, Terrestrial- Chemicals Monitoring & Transport- (1990-) ; ABSORPTION ; ALKYLATED AROMATICS ; Analysis methods ; Applied sciences ; AROMATICS ; BENZENE ; CONTAMINATION ; DATA ; DESIGN ; EMISSION SPECTRA ; ENVIRONMENTAL SCIENCES ; Exact sciences and technology ; EXPERIMENTAL DATA ; FIBER OPTICS ; FIELD TESTS ; FLUORESCENCE ; FUELS ; GASOLINE ; GROUND WATER ; HYDROCARBONS ; HYDROGEN COMPOUNDS ; INFORMATION ; LEAKS ; LIQUID FUELS ; LUMINESCENCE ; MATTER ; MEASURING INSTRUMENTS ; MEASURING METHODS ; Natural water pollution ; NUMERICAL DATA ; OIL SPILLS ; ORGANIC COMPOUNDS ; OTHER INSTRUMENTATION ; OXYGEN COMPOUNDS ; PETROLEUM PRODUCTS ; Pollution ; POLYMERS ; PORTABLE EQUIPMENT ; SOILS ; SPECTRA ; STORAGE ; TEMPERATURE DEPENDENCE ; TESTING ; TOLUENE ; UNDERGROUND STORAGE ; VOLATILE MATTER ; WATER ; Water treatment and pollution ; XYLENES</subject><ispartof>Environmental science & technology, 1991-07, Vol.25 (7), p.1301-1304</ispartof><rights>1991 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a402t-158015a38230788874af30f73b8880587fe5e200e2627ef949e8ec83cb3811ca3</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/es00019a012$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/es00019a012$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,777,781,882,2752,27057,27905,27906,56719,56769</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=19851166$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5392808$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Barnard, Steven M</creatorcontrib><creatorcontrib>Walt, David R</creatorcontrib><title>Fiber-optic organic vapor sensor</title><title>Environmental science & technology</title><addtitle>Environ. Sci. Technol</addtitle><description>The application of fibre-optic technology to the monitoring of volatile organic compounds in soil groundwater samples is described. Sensors and supporting portable instruments suitable for field applications were developed for continuous in-situ measurements. The sensor's operation depends on fluorescence modulation in the presence of volatile organic vapours. Polymer absorption of organic vapours results in a concomitant enhancement of fluorescence in an immobilized fluorophor. In-situ field tests conducted at a jet fuel contamination site showed a detection limit of 10 ppm and a response time of 2.5 minutes with 7.5 per cent signal change.</description><subject>02 PETROLEUM</subject><subject>020900 - Petroleum- Environmental Aspects</subject><subject>440800 - Miscellaneous Instrumentation- (1990-)</subject><subject>540220 - Environment, Terrestrial- Chemicals Monitoring & Transport- (1990-)</subject><subject>ABSORPTION</subject><subject>ALKYLATED AROMATICS</subject><subject>Analysis methods</subject><subject>Applied sciences</subject><subject>AROMATICS</subject><subject>BENZENE</subject><subject>CONTAMINATION</subject><subject>DATA</subject><subject>DESIGN</subject><subject>EMISSION SPECTRA</subject><subject>ENVIRONMENTAL SCIENCES</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>FIBER OPTICS</subject><subject>FIELD TESTS</subject><subject>FLUORESCENCE</subject><subject>FUELS</subject><subject>GASOLINE</subject><subject>GROUND WATER</subject><subject>HYDROCARBONS</subject><subject>HYDROGEN COMPOUNDS</subject><subject>INFORMATION</subject><subject>LEAKS</subject><subject>LIQUID FUELS</subject><subject>LUMINESCENCE</subject><subject>MATTER</subject><subject>MEASURING INSTRUMENTS</subject><subject>MEASURING METHODS</subject><subject>Natural water pollution</subject><subject>NUMERICAL DATA</subject><subject>OIL SPILLS</subject><subject>ORGANIC COMPOUNDS</subject><subject>OTHER INSTRUMENTATION</subject><subject>OXYGEN COMPOUNDS</subject><subject>PETROLEUM PRODUCTS</subject><subject>Pollution</subject><subject>POLYMERS</subject><subject>PORTABLE EQUIPMENT</subject><subject>SOILS</subject><subject>SPECTRA</subject><subject>STORAGE</subject><subject>TEMPERATURE DEPENDENCE</subject><subject>TESTING</subject><subject>TOLUENE</subject><subject>UNDERGROUND STORAGE</subject><subject>VOLATILE MATTER</subject><subject>WATER</subject><subject>Water treatment and pollution</subject><subject>XYLENES</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1991</creationdate><recordtype>article</recordtype><recordid>eNqN0U1LAzEQBuAgCtbqyT9QBPUgq_nYbLJHKVbFVoVW9BbSMKtb282a2Yr-eyNb1IOgpyHJk5dhhpBdRo8Z5ewEkFLKcksZXyMdJjlNpJZsnXTitUhykT1ski3EWWRcUN0hvUE5hZD4uildz4dHW8X6amsfeggV-rBNNgo7R9hZ1S65G5xN-hfJ8Ob8sn86TGxKeZMwqSmTVugYq7TWKrWFoIUS03igUqsCJHBKgWdcQZGnOWhwWrip0Iw5K7pkr8312JQGXdmAe3K-qsA1Roqca6ojOmhRHfzLErAxixIdzOe2Ar9EwzKupeT8b5hyxVP1DyhUlIpFeNRCFzxigMLUoVzY8G4YNZ_DNz-GH_X-Ktais_Mi2MqV-P0lj1thWRZd0roSG3j7erfh2WRKKGkmt2Mzur8ej6S6MuPoD1tvHZqZX4Yq7uTXDj4AOSSbYw</recordid><startdate>19910701</startdate><enddate>19910701</enddate><creator>Barnard, Steven M</creator><creator>Walt, David R</creator><general>American Chemical Society</general><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7T2</scope><scope>7TV</scope><scope>7U2</scope><scope>OTOTI</scope></search><sort><creationdate>19910701</creationdate><title>Fiber-optic organic vapor sensor</title><author>Barnard, Steven M ; Walt, David R</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a402t-158015a38230788874af30f73b8880587fe5e200e2627ef949e8ec83cb3811ca3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1991</creationdate><topic>02 PETROLEUM</topic><topic>020900 - Petroleum- Environmental Aspects</topic><topic>440800 - Miscellaneous Instrumentation- (1990-)</topic><topic>540220 - Environment, Terrestrial- Chemicals Monitoring & Transport- (1990-)</topic><topic>ABSORPTION</topic><topic>ALKYLATED AROMATICS</topic><topic>Analysis methods</topic><topic>Applied sciences</topic><topic>AROMATICS</topic><topic>BENZENE</topic><topic>CONTAMINATION</topic><topic>DATA</topic><topic>DESIGN</topic><topic>EMISSION SPECTRA</topic><topic>ENVIRONMENTAL SCIENCES</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>FIBER OPTICS</topic><topic>FIELD TESTS</topic><topic>FLUORESCENCE</topic><topic>FUELS</topic><topic>GASOLINE</topic><topic>GROUND WATER</topic><topic>HYDROCARBONS</topic><topic>HYDROGEN COMPOUNDS</topic><topic>INFORMATION</topic><topic>LEAKS</topic><topic>LIQUID FUELS</topic><topic>LUMINESCENCE</topic><topic>MATTER</topic><topic>MEASURING INSTRUMENTS</topic><topic>MEASURING METHODS</topic><topic>Natural water pollution</topic><topic>NUMERICAL DATA</topic><topic>OIL SPILLS</topic><topic>ORGANIC COMPOUNDS</topic><topic>OTHER INSTRUMENTATION</topic><topic>OXYGEN COMPOUNDS</topic><topic>PETROLEUM PRODUCTS</topic><topic>Pollution</topic><topic>POLYMERS</topic><topic>PORTABLE EQUIPMENT</topic><topic>SOILS</topic><topic>SPECTRA</topic><topic>STORAGE</topic><topic>TEMPERATURE DEPENDENCE</topic><topic>TESTING</topic><topic>TOLUENE</topic><topic>UNDERGROUND STORAGE</topic><topic>VOLATILE MATTER</topic><topic>WATER</topic><topic>Water treatment and pollution</topic><topic>XYLENES</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barnard, Steven M</creatorcontrib><creatorcontrib>Walt, David R</creatorcontrib><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Aqualine</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Health and Safety Science Abstracts (Full archive)</collection><collection>Pollution Abstracts</collection><collection>Safety Science and Risk</collection><collection>OSTI.GOV</collection><jtitle>Environmental science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barnard, Steven M</au><au>Walt, David R</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Fiber-optic organic vapor sensor</atitle><jtitle>Environmental science & technology</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>1991-07-01</date><risdate>1991</risdate><volume>25</volume><issue>7</issue><spage>1301</spage><epage>1304</epage><pages>1301-1304</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>The application of fibre-optic technology to the monitoring of volatile organic compounds in soil groundwater samples is described. Sensors and supporting portable instruments suitable for field applications were developed for continuous in-situ measurements. The sensor's operation depends on fluorescence modulation in the presence of volatile organic vapours. Polymer absorption of organic vapours results in a concomitant enhancement of fluorescence in an immobilized fluorophor. In-situ field tests conducted at a jet fuel contamination site showed a detection limit of 10 ppm and a response time of 2.5 minutes with 7.5 per cent signal change.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/es00019a012</doi><tpages>4</tpages></addata></record> |
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source | American Chemical Society Journals |
subjects | 02 PETROLEUM 020900 - Petroleum- Environmental Aspects 440800 - Miscellaneous Instrumentation- (1990-) 540220 - Environment, Terrestrial- Chemicals Monitoring & Transport- (1990-) ABSORPTION ALKYLATED AROMATICS Analysis methods Applied sciences AROMATICS BENZENE CONTAMINATION DATA DESIGN EMISSION SPECTRA ENVIRONMENTAL SCIENCES Exact sciences and technology EXPERIMENTAL DATA FIBER OPTICS FIELD TESTS FLUORESCENCE FUELS GASOLINE GROUND WATER HYDROCARBONS HYDROGEN COMPOUNDS INFORMATION LEAKS LIQUID FUELS LUMINESCENCE MATTER MEASURING INSTRUMENTS MEASURING METHODS Natural water pollution NUMERICAL DATA OIL SPILLS ORGANIC COMPOUNDS OTHER INSTRUMENTATION OXYGEN COMPOUNDS PETROLEUM PRODUCTS Pollution POLYMERS PORTABLE EQUIPMENT SOILS SPECTRA STORAGE TEMPERATURE DEPENDENCE TESTING TOLUENE UNDERGROUND STORAGE VOLATILE MATTER WATER Water treatment and pollution XYLENES |
title | Fiber-optic organic vapor sensor |
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