Reaction of Zirconium Fluoride Monohydrate and Ammonium Bifluoride: Its Effect on Fluoride Glass Preparation and Quality

The products obtained from the roomtemperature reaction of ammonium bifluoride and zirconium fluoride monohydrate are ammonium heptafluorozirconate ((NH4)3ZrF2), liquid water, and hydrogen fluoride. Ammonium bifluoride and zirconium fluoride monohydrate were reacted prior to glass batching, producin...

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Veröffentlicht in:	Journal of the American Ceramic Society 1989-08, Vol.72 (8), p.1441-1443
Hauptverfasser:	Ewing, Kenneth J., Sanghera, Jasbinder S., Miklos, Robert E., Sachon, Maria G., Peitersen, Laura, Hart, Patricia, Aggarwal, Ishwar
Format:	Artikel
Sprache:	eng
Schlagworte:	360201 - Ceramics, Cermets, & Refractories- Preparation & Fabrication 360202 - Ceramics, Cermets, & Refractories- Structure & Phase Studies 400201 - Chemical & Physicochemical Properties ammonium AMMONIUM COMPOUNDS AMMONIUM FLUORIDES Applied sciences Building materials. Ceramics. Glasses CHEMICAL COMPOSITION Chemical industry and chemicals Exact sciences and technology FLUORIDES FLUORINE COMPOUNDS GLASS Glasses HALIDES HALOGEN COMPOUNDS HYDRATES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY Manufacture MATERIALS SCIENCE PROCESSING TRANSITION ELEMENT COMPOUNDS zirconium ZIRCONIUM COMPOUNDS ZIRCONIUM FLUORIDES
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Beschreibung
Zusammenfassung:	The products obtained from the roomtemperature reaction of ammonium bifluoride and zirconium fluoride monohydrate are ammonium heptafluorozirconate ((NH4)3ZrF2), liquid water, and hydrogen fluoride. Ammonium bifluoride and zirconium fluoride monohydrate were reacted prior to glass batching, producing dry ammonium heptafluorozirconate which was used to prepare a high‐quality ZBLAN fluoride glass.
ISSN:	0002-7820 1551-2916
DOI:	10.1111/j.1151-2916.1989.tb07670.x