Electron transfer across polypeptides. 6. Long-range electron transfer in osmium-ruthenium binuclear complexes bridged with oligoproline peptides

A series of binuclear ((NH sub(3)) sub(5)Os(Pro) sub(n)Co(NH sub(3)) sub(5)) (CF sub(3)COO) sub(5) (n = 0-4) complexes have been synthesized. Long range intramolecular electron transfer reactions in these polypeptides were studied.

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Bibliographische Detailangaben
Veröffentlicht in:	Journal of the American Chemical Society 1990-09, Vol.112 (20), p.7278-7286
Hauptverfasser:	Vassilian, Asbed, Wishart, James F, Van Hemelryck, Bruno, Schwarz, Harold, Isied, Stephan S
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties 400600 - Radiation Chemistry 550200 - Biochemistry BASIC BIOLOGICAL SCIENCES CHEMICAL PREPARATION CHEMICAL RADIATION EFFECTS CHEMICAL REACTIONS COMPLEXES DECOMPOSITION ELECTRON TRANSFER INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ORGANIC COMPOUNDS osmium OSMIUM COMPLEXES PEPTIDES POLYPEPTIDES proline PROTEINS RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY RADIATION EFFECTS RADICALS RADIOLYSIS RUTHENIUM COMPLEXES SYNTHESIS TRANSITION ELEMENT COMPLEXES
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Zusammenfassung:	A series of binuclear ((NH sub(3)) sub(5)Os(Pro) sub(n)Co(NH sub(3)) sub(5)) (CF sub(3)COO) sub(5) (n = 0-4) complexes have been synthesized. Long range intramolecular electron transfer reactions in these polypeptides were studied.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja00176a030