Preparation of superconductor/polymer composite with resistive transition temperature (Tc) above 77 K

Sintered Y sub 1 Ba sub 2 Cu sub 3 O sub 7 sub - sub x disk is impregnated with low-viscosity 2-ethylhexyl acrylate monomer containing benzoyl peroxide and dicumyl peroxide as polymerization catalysts under moderate vacuum for 30 min followed by an overnight soaking. The polymerization treatment con...

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Veröffentlicht in:Journal of the American Ceramic Society 1989-07, Vol.72 (7), p.1247-1248
Hauptverfasser: SARKAR, A. K, SALYER, I. O, BINOD KUMAR
Format: Artikel
Sprache:eng
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Zusammenfassung:Sintered Y sub 1 Ba sub 2 Cu sub 3 O sub 7 sub - sub x disk is impregnated with low-viscosity 2-ethylhexyl acrylate monomer containing benzoyl peroxide and dicumyl peroxide as polymerization catalysts under moderate vacuum for 30 min followed by an overnight soaking. The polymerization treatment consists of a heat treatment at 60 degrees C for 24 h followed by a second heat treatment at 80 degrees for 8- 10 h. The composite specimens exhibit superconducting resistive transition at approximately 80 K. SEM reveals excellent wetting, infiltration, and polymerization of the monomer into the superconducting material.
ISSN:0002-7820
1551-2916
DOI:10.1111/j.1151-2916.1989.tb09717.x