Octanol-water partition coefficients of polychlorinated biphenyl congeners
Octanol-water partition coefficients (Kow) were accurately determined by the generator column technique for 13 PCB congeners. These values were used to confirm a significant linear relationship between log Kow and the logarithm of the relative retention time on a nonselective gas chromatographic sta...
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| Veröffentlicht in: | Environmental science & technology 1988-04, Vol.22 (4), p.382-387 |
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| container_title | Environmental science & technology |
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| creator | Hawker, Darryl W Connell, Des W |
| description | Octanol-water partition coefficients (Kow) were accurately determined by the generator column technique for 13 PCB congeners. These values were used to confirm a significant linear relationship between log Kow and the logarithm of the relative retention time on a nonselective gas chromatographic stationary phase. The total surface areas for all the congeners were determined; the total surface area was highly significantly correlated with log Kow. Further development of this relationships yields expressions for aqueous solubility which can be used to compute the solubility for those PCBs where appropriate data are available. |
| doi_str_mv | 10.1021/es00169a004 |
| format | Article |
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These values were used to confirm a significant linear relationship between log Kow and the logarithm of the relative retention time on a nonselective gas chromatographic stationary phase. The total surface areas for all the congeners were determined; the total surface area was highly significantly correlated with log Kow. Further development of this relationships yields expressions for aqueous solubility which can be used to compute the solubility for those PCBs where appropriate data are available.</description><identifier>ISSN: 0013-936X</identifier><identifier>EISSN: 1520-5851</identifier><identifier>DOI: 10.1021/es00169a004</identifier><identifier>CODEN: ESTHAG</identifier><language>eng</language><publisher>Washington, DC: American Chemical Society</publisher><subject>400201 - Chemical & Physicochemical Properties ; AQUEOUS SOLUTIONS ; AROMATICS ; BIFENILOS POLICLORADOS ; CHEMICAL PROPERTIES ; CHEMICOPHYSICAL PROPERTIES ; Chemistry ; CHLORINATED AROMATIC HYDROCARBONS ; CONTAMINACION ; DATA ; DISPERSIONS ; Exact sciences and technology ; EXPERIMENTAL DATA ; HALOGENATED AROMATIC HYDROCARBONS ; INFORMATION ; INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ; MIXTURES ; Noncondensed benzenic compounds ; NUMERICAL DATA ; Organic chemistry ; ORGANIC CHLORINE COMPOUNDS ; ORGANIC COMPOUNDS ; ORGANIC HALOGEN COMPOUNDS ; PARTITION ; POLLUTION ; POLYCHLORINATED BIPHENYLS ; POLYCHLORURE DE BIPHENYLE ; Preparations and properties ; PROPIEDADES FISICO-QUIMICAS ; PROPRIETE PHYSICO-CHIMIQUE ; SOLUBILITY ; SOLUTIONS</subject><ispartof>Environmental science & technology, 1988-04, Vol.22 (4), p.382-387</ispartof><rights>1989 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-a504t-941288d49f3a7b87b95f4d696fd6cb4c9b16ebd318fe0dac5d302209c87173573</citedby></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://pubs.acs.org/doi/pdf/10.1021/es00169a004$$EPDF$$P50$$Gacs$$H</linktopdf><linktohtml>$$Uhttps://pubs.acs.org/doi/10.1021/es00169a004$$EHTML$$P50$$Gacs$$H</linktohtml><link.rule.ids>230,314,776,780,881,2751,27055,27903,27904,56717,56767</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=7040500$$DView record in Pascal Francis$$Hfree_for_read</backlink><backlink>$$Uhttps://www.osti.gov/biblio/5239590$$D View this record in Osti.gov$$Hfree_for_read</backlink></links><search><creatorcontrib>Hawker, Darryl W</creatorcontrib><creatorcontrib>Connell, Des W</creatorcontrib><title>Octanol-water partition coefficients of polychlorinated biphenyl congeners</title><title>Environmental science & technology</title><addtitle>Environ. Sci. Technol</addtitle><description>Octanol-water partition coefficients (Kow) were accurately determined by the generator column technique for 13 PCB congeners. These values were used to confirm a significant linear relationship between log Kow and the logarithm of the relative retention time on a nonselective gas chromatographic stationary phase. The total surface areas for all the congeners were determined; the total surface area was highly significantly correlated with log Kow. Further development of this relationships yields expressions for aqueous solubility which can be used to compute the solubility for those PCBs where appropriate data are available.</description><subject>400201 - Chemical & Physicochemical Properties</subject><subject>AQUEOUS SOLUTIONS</subject><subject>AROMATICS</subject><subject>BIFENILOS POLICLORADOS</subject><subject>CHEMICAL PROPERTIES</subject><subject>CHEMICOPHYSICAL PROPERTIES</subject><subject>Chemistry</subject><subject>CHLORINATED AROMATIC HYDROCARBONS</subject><subject>CONTAMINACION</subject><subject>DATA</subject><subject>DISPERSIONS</subject><subject>Exact sciences and technology</subject><subject>EXPERIMENTAL DATA</subject><subject>HALOGENATED AROMATIC HYDROCARBONS</subject><subject>INFORMATION</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>MIXTURES</subject><subject>Noncondensed benzenic compounds</subject><subject>NUMERICAL DATA</subject><subject>Organic chemistry</subject><subject>ORGANIC CHLORINE COMPOUNDS</subject><subject>ORGANIC COMPOUNDS</subject><subject>ORGANIC HALOGEN COMPOUNDS</subject><subject>PARTITION</subject><subject>POLLUTION</subject><subject>POLYCHLORINATED BIPHENYLS</subject><subject>POLYCHLORURE DE BIPHENYLE</subject><subject>Preparations and properties</subject><subject>PROPIEDADES FISICO-QUIMICAS</subject><subject>PROPRIETE PHYSICO-CHIMIQUE</subject><subject>SOLUBILITY</subject><subject>SOLUTIONS</subject><issn>0013-936X</issn><issn>1520-5851</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1988</creationdate><recordtype>article</recordtype><recordid>eNqN0c9rFDEUB_AgCq7VkzdPg4g9yOjLr5nkKOuPWhYqtEVvIZNJuqnTZEyy2P3vzTqlePDg6cF7n3x5vCD0HMNbDAS_sxkAd1IDsAdohTmBlguOH6JV7dNW0u77Y_Qk52sAIBTECp2emaJDnNpfutjUzDoVX3wMjYnWOW-8DSU30TVznPZmO8XkQ5VjM_h5a8N-qjBc2WBTfooeOT1l--yuHqHLTx8v1ift5uzzl_X7Tas5sNJKhokQI5OO6n4Q_SC5Y2MnOzd2ZmBGDrizw0ixcBZGbfhIgRCQRvS4p7ynR-jlkhtz8SobX6zZ1i2CNUVxQiWXUNHrBc0p_tzZXNSNz8ZOkw427rLCTEhCxP9AQgj_A98s0KSYc7JOzcnf6LRXGNTh-uqv61f96i5WZ6Mnl3QwPt8_6YEBh0NouzCfi729H-v0Q3U97bm6-Hqu6Idv8mR9itWm-heLdzoqfZVq5OW5EJRhegg7XobaZHUddynUb_jndr8ButSngw</recordid><startdate>19880401</startdate><enddate>19880401</enddate><creator>Hawker, Darryl W</creator><creator>Connell, Des W</creator><general>American Chemical Society</general><scope>FBQ</scope><scope>BSCLL</scope><scope>IQODW</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7T2</scope><scope>7TV</scope><scope>7U2</scope><scope>OTOTI</scope></search><sort><creationdate>19880401</creationdate><title>Octanol-water partition coefficients of polychlorinated biphenyl congeners</title><author>Hawker, Darryl W ; Connell, Des W</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a504t-941288d49f3a7b87b95f4d696fd6cb4c9b16ebd318fe0dac5d302209c87173573</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1988</creationdate><topic>400201 - Chemical & Physicochemical Properties</topic><topic>AQUEOUS SOLUTIONS</topic><topic>AROMATICS</topic><topic>BIFENILOS POLICLORADOS</topic><topic>CHEMICAL PROPERTIES</topic><topic>CHEMICOPHYSICAL PROPERTIES</topic><topic>Chemistry</topic><topic>CHLORINATED AROMATIC HYDROCARBONS</topic><topic>CONTAMINACION</topic><topic>DATA</topic><topic>DISPERSIONS</topic><topic>Exact sciences and technology</topic><topic>EXPERIMENTAL DATA</topic><topic>HALOGENATED AROMATIC HYDROCARBONS</topic><topic>INFORMATION</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>MIXTURES</topic><topic>Noncondensed benzenic compounds</topic><topic>NUMERICAL DATA</topic><topic>Organic chemistry</topic><topic>ORGANIC CHLORINE COMPOUNDS</topic><topic>ORGANIC COMPOUNDS</topic><topic>ORGANIC HALOGEN COMPOUNDS</topic><topic>PARTITION</topic><topic>POLLUTION</topic><topic>POLYCHLORINATED BIPHENYLS</topic><topic>POLYCHLORURE DE BIPHENYLE</topic><topic>Preparations and properties</topic><topic>PROPIEDADES FISICO-QUIMICAS</topic><topic>PROPRIETE PHYSICO-CHIMIQUE</topic><topic>SOLUBILITY</topic><topic>SOLUTIONS</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Hawker, Darryl W</creatorcontrib><creatorcontrib>Connell, Des W</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Pascal-Francis</collection><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Health and Safety Science Abstracts (Full archive)</collection><collection>Pollution Abstracts</collection><collection>Safety Science and Risk</collection><collection>OSTI.GOV</collection><jtitle>Environmental science & technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hawker, Darryl W</au><au>Connell, Des W</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Octanol-water partition coefficients of polychlorinated biphenyl congeners</atitle><jtitle>Environmental science & technology</jtitle><addtitle>Environ. Sci. Technol</addtitle><date>1988-04-01</date><risdate>1988</risdate><volume>22</volume><issue>4</issue><spage>382</spage><epage>387</epage><pages>382-387</pages><issn>0013-936X</issn><eissn>1520-5851</eissn><coden>ESTHAG</coden><abstract>Octanol-water partition coefficients (Kow) were accurately determined by the generator column technique for 13 PCB congeners. These values were used to confirm a significant linear relationship between log Kow and the logarithm of the relative retention time on a nonselective gas chromatographic stationary phase. The total surface areas for all the congeners were determined; the total surface area was highly significantly correlated with log Kow. Further development of this relationships yields expressions for aqueous solubility which can be used to compute the solubility for those PCBs where appropriate data are available.</abstract><cop>Washington, DC</cop><pub>American Chemical Society</pub><doi>10.1021/es00169a004</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0013-936X |
| ispartof | Environmental science & technology, 1988-04, Vol.22 (4), p.382-387 |
| issn | 0013-936X 1520-5851 |
| language | eng |
| recordid | cdi_osti_scitechconnect_5239590 |
| source | American Chemical Society Journals |
| subjects | 400201 - Chemical & Physicochemical Properties AQUEOUS SOLUTIONS AROMATICS BIFENILOS POLICLORADOS CHEMICAL PROPERTIES CHEMICOPHYSICAL PROPERTIES Chemistry CHLORINATED AROMATIC HYDROCARBONS CONTAMINACION DATA DISPERSIONS Exact sciences and technology EXPERIMENTAL DATA HALOGENATED AROMATIC HYDROCARBONS INFORMATION INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY MIXTURES Noncondensed benzenic compounds NUMERICAL DATA Organic chemistry ORGANIC CHLORINE COMPOUNDS ORGANIC COMPOUNDS ORGANIC HALOGEN COMPOUNDS PARTITION POLLUTION POLYCHLORINATED BIPHENYLS POLYCHLORURE DE BIPHENYLE Preparations and properties PROPIEDADES FISICO-QUIMICAS PROPRIETE PHYSICO-CHIMIQUE SOLUBILITY SOLUTIONS |
| title | Octanol-water partition coefficients of polychlorinated biphenyl congeners |
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