Formation of nitroarenes during ambient high-volume sampling

The formation of nitroarenes during high-volume sampling conditions has been evaluated. Perdeuteriated fluoranthene, pyrene, benzo(a)pyrene, and perylene were coated onto filters loaded with previously collected particles and exposed to ambient gases during additional high-volume sampling. Deuteriat...

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Veröffentlicht in:	Environmental science & technology 1988-04, Vol.22 (4), p.457-462
Hauptverfasser:	Arey, Janet, Zielinska, Barbara, Atkinson, Roger, Winer, Arthur M
Format:	Artikel
Sprache:	eng
Schlagworte:	400201 - Chemical & Physicochemical Properties 540111 - Environment, Atmospheric- Basic Studies- Radiometric Techniques- (1990-) air pollution AIR POLLUTION MONITORING AIR SAMPLERS analisis quimico analyse chimique Applied sciences AROMATICS Atmospheric pollution BENZOPYRENE california californie CHALCOGENIDES chemical analysis CHEMICAL REACTION YIELD CHEMICAL REACTIONS compose organoazote compuesto organico del nitrogeno CONDENSED AROMATICS contaminacion del aire DEUTERIUM COMPOUNDS echantillonnage ENVIRONMENTAL SCIENCES Exact sciences and technology HYDROCARBONS HYDROGEN COMPOUNDS INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY ISOTOPE APPLICATIONS muestreo NITRATION NITRO COMPOUNDS NITROGEN COMPOUNDS NITROGEN OXIDES ORGANIC COMPOUNDS ORGANIC NITROGEN COMPOUNDS OXIDES OXYGEN COMPOUNDS PARTICLES PARTICULATES PERYLENE Pollutants physicochemistry study: properties, effects, reactions, transport and distribution Pollution pollution atmospherique POLLUTION SOURCES POLYCYCLIC AROMATIC HYDROCARBONS PYRENE SAMPLERS sampling TRACER TECHNIQUES YIELDS
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Zusammenfassung:	The formation of nitroarenes during high-volume sampling conditions has been evaluated. Perdeuteriated fluoranthene, pyrene, benzo(a)pyrene, and perylene were coated onto filters loaded with previously collected particles and exposed to ambient gases during additional high-volume sampling. Deuteriated nitro products were formed from pyrene, benzo(a)pyrene, and perylene during 7-10-h exposure/sampling periods in Torrance, CA, during a wintertime high-NO sub(x) episode. No formation of nitrofluoranthenes was observed, and it is calculated that < 3% of the 1-nitropyrene collected during such a pollution episode was formed during collection.
ISSN:	0013-936X 1520-5851
DOI:	10.1021/es00169a015