Xenon Hexafluoride

The preparation and properties of XeF6 are reported. Reactions were carried out in a stainless steel vessel at 1000 psi and 350 to 450 deg C. In all cases a mixture of volatile products was obtained. The more volatile fractions always concentrated XeF6. The purity of the samples was monitored by inf...

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Veröffentlicht in:	Journal of the American Chemical Society 1963-01, Vol.85 (1), p.111-112
Hauptverfasser:	Weaver, E. Eugene, Weinstock, Bernard, Knop, Charles P
Format:	Artikel
Sprache:	eng
Schlagworte:	CHEMICAL REACTIONS HYDROFLUORIC ACID HYDROGEN IMPURITIES INFRARED RADIATION INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY LATTICES PREPARATION PRESSURE QUALITATIVE ANALYSIS REDUCTION SPECTROSCOPY STAINLESS STEELS TEMPERATURE VAPORS VESSELS VOLATILITY XENON XENON FLUORIDES
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Beschreibung
Zusammenfassung:	The preparation and properties of XeF6 are reported. Reactions were carried out in a stainless steel vessel at 1000 psi and 350 to 450 deg C. In all cases a mixture of volatile products was obtained. The more volatile fractions always concentrated XeF6. The purity of the samples was monitored by infrared spectroscopy. In the purest XeF6 sample, the twin bands, nu 2 + nu 3 and nu 1 + nu 3 were observe d at 1154 and 1189 cm -1. The formula for XeF6 was established by chemical analysis. The compound can be reduced with H2 to form HF and Xe. Preliminary vapor pressure measurements gave: 0 deg C, 6mm; and 20 deg C, 27 mm.
ISSN:	0002-7863 1520-5126
DOI:	10.1021/ja00884a025