Iron-modified biochar-based bilayer permeable reactive barrier for Cr(VI) removal

Iron (Fe)-modified biochar (FeBC) has been developed to remove hexavalent chromium (Cr(VI)) from groundwater and is suitable for use in permeable reactive barriers (PRBs). However, Cr(VI) removal behavior and chemical processes in FeBC-based PRBs are not fully understood, and the potential for Fe release has not been addressed. In this study, three FeBC-based PRBs were assessed in column experiments for 563 days with respect to their ability to remove Cr(VI). Bilayer column filled with FeBC+limestone and BC+limestone in two separate layers (FeBC_Ca_BC) showed the best performance in terms of Cr(VI) removal with a low treatment cost. The corrosion of FeBC was mainly related to pH and Cr(VI) concentration rather than flow rate. Leached Fe was attenuated by BC and limestone and reutilized in FeBC_Ca_BC. Cr(VI) was reduced to Cr(III) and then adsorbed or precipitated on the biochars. Cr and Fe formed inner-sphere complexes and then transformed from double corner sharing to edge sharing. During the reaction, Cr penetrated from the surface to the interior of the biochars and became a more stable species. This study provides evidence of the effectiveness of a new combination of biochars for Cr(VI) removal and insights into the reaction mechanisms. [Display omitted] •Cr(VI) was continuously removed by FeBC-based PRB in 563 days (200 PVs).•XAS reveal Cr was reduced to Cr(III) and co-precipitated with Fe as CrnFe(1−n)(OOH).•Cr-Fe complex underwent a transformation from double corner sharing to edge sharing.•Cr exists in a stable form and diffuses into the interior of FeBC over time.•The enhancement mechanisms include the immobilization and reuse of leached Fe.