Synthesis and structural characterization of a Cu(I) complex with 4-(1H-imidazol-1-yl)phenyl)methanone ligands
A copper complex with V -shaped ligands, [( L 1 )Cu 2 Cl 2 ] n ( 1 ), ( L 1 = 4-(1 H -imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. C 2/ c with the unit cell...
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| Veröffentlicht in: | Crystallography reports 2017-11, Vol.62 (6), p.881-884 |
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| Hauptverfasser: | , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A copper complex with
V
-shaped ligands, [(
L
1
)Cu
2
Cl
2
]
n
(
1
), (
L
1 = 4-(1
H
-imidazol-1-yl)phenyl) methanone) has been synthesized and characterized by IR spectroscopy, elemental analyses and singlecrystal X-ray diffraction. The crystal of
1
is monoclinic, sp. gr.
C
2/
c
with the unit cell parameters
a
= 17.9496(13),
b
= 15.3440(13),
c
= 7.2983(7) Å, and β = 112.875(6)°,
Z
= 4,
R
1
= 0.0681, and
wR
2
= 0.1736 (
I
> 2 σ). The solid state structure of
1
consists of 2D metal aromatic chloride layers, which are propagating along the
bc
plane to form a 3D network through hydrogen bonds. |
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| ISSN: | 1063-7745 1562-689X |
| DOI: | 10.1134/S1063774517060268 |