Features of {sup 63,65}Cu NMR Spectra in the Local Field of Samples of CuFeS{sub 2} Semiconductor Mineral from Oceanic Sulfide Deposits

The results of studying natural samples of CuFeS{sub 2} chalcopyrite mineral from hydrothermal ore manifestations of island arcs of the Pacific Ocean by {sup 63}Cu nuclear magnetic resonance ({sup 63}Cu NMR) in a local field at room temperature are presented. The asymmetric shape of the detected res...

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Veröffentlicht in:Semiconductors (Woodbury, N.Y.) N.Y.), 2018-08, Vol.52 (8)
Hauptverfasser: Matukhin, V. L., Pogoreltsev, A. I., Gavrilenko, A. N., Garkavyi, S. O., Shmidt, E. V., Babaeva, S. F., Sukhanova, A. A., Terukov, E. I.
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Sprache:eng
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Zusammenfassung:The results of studying natural samples of CuFeS{sub 2} chalcopyrite mineral from hydrothermal ore manifestations of island arcs of the Pacific Ocean by {sup 63}Cu nuclear magnetic resonance ({sup 63}Cu NMR) in a local field at room temperature are presented. The asymmetric shape of the detected resonance lines in the {sup 63}Cu NMR spectrum indicates the presence of at least two overlapping lines. The presence of two overlapping central components can be a consequence of the occurrence of regions with different types of structural distortion near the resonant nuclei. These results show that the pulsed {sup 63}Cu NMR method can be an effective method for studying the physical properties of deep-sea polymetallic sulfides of the global ocean.
ISSN:1063-7826
1090-6479
DOI:10.1134/S1063782618080134