Charge transport and memristive properties of graphene quantum dots embedded in poly(3-hexylthiophene) matrix

We show that graphene quantum dots (GQD) embedded in a semiconducting poly(3-hexylthiophene) polymeric matrix act as charge trapping nanomaterials. In plane current-voltage (I-V) measurements of thin films realized from this nanocomposite deposited on gold interdigitated electrodes revealed that the...

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Veröffentlicht in:Applied physics letters 2014-08, Vol.105 (8)
Hauptverfasser: Cosmin Obreja, Alexandru, Cristea, Dana, Mihalache, Iuliana, Radoi, Antonio, Gavrila, Raluca, Comanescu, Florin, Kusko, Cristian
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container_issue 8
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container_title Applied physics letters
container_volume 105
creator Cosmin Obreja, Alexandru
Cristea, Dana
Mihalache, Iuliana
Radoi, Antonio
Gavrila, Raluca
Comanescu, Florin
Kusko, Cristian
description We show that graphene quantum dots (GQD) embedded in a semiconducting poly(3-hexylthiophene) polymeric matrix act as charge trapping nanomaterials. In plane current-voltage (I-V) measurements of thin films realized from this nanocomposite deposited on gold interdigitated electrodes revealed that the GQD enhanced dramatically the hole transport. I-V characteristics exhibited a strong nonlinear behavior and a pinched hysteresis loop, a signature of a memristive response. The transport properties of this nanocomposite were explained in terms of a trap controlled space charge limited current mechanism.
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subjects Applied physics
CHARGE TRANSPORT
CURRENTS
ELECTRIC CONDUCTIVITY
ELECTRIC POTENTIAL
GOLD
GRAPHENE
HYSTERESIS
Hysteresis loops
MATRIX MATERIALS
NANOCOMPOSITES
Nanomaterials
NANOSCIENCE AND NANOTECHNOLOGY
NONLINEAR PROBLEMS
QUANTUM DOTS
SPACE CHARGE
THIN FILMS
TRAPPING
title Charge transport and memristive properties of graphene quantum dots embedded in poly(3-hexylthiophene) matrix
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