Effects of A-site composition and oxygen nonstoichiometry on the thermodynamic stability of compounds in the Ba–Sr–Co–Fe–O system

The thermodynamic stability of the perovskite-type oxides in the BaxSr1−xCo0.8Fe0.2O3−δ (BSCF) system was investigated with varying Ba:Sr ratios (x=0.2, 0.4, 0.5, 0.6, 0.8) and correlated with the charge compensation mechanism and the change in the oxygen stoichiometry of the materials. Thermodynamic properties represented by the relative partial molar free energies, enthalpies and entropies of oxygen dissolution in the perovskite phase, as well as the equilibrium partial pressures of oxygen have been obtained in the temperature range of 823–1273K using solid electrolyte electrochemical cells (EMF) method. The influence of the oxygen stoichiometry change on the thermodynamic properties was examined using a coulometric titration technique coupled with EMF measurements. The temperature dependence of enthalpy increment (HT−H298) in the temperature range of 700–900K was measured by drop calorimetry. The energetic parameters allow for the correlation of the structural and electrical stability with the defect structures. Partial molar energy of oxygen dissolution (ΔG¯O2) (EMF measurements) and enthalpy increment (HT−H298) (drop calorimetry data) of perovskite materials with the composition BaxSr1−xCo0.8Fe0.2O3−δ as a function of temperature and Barium content. [Display omitted] ► We report relevant data for thermodynamic stability of BaxSr1−xCo1−yFeyO3−δ compounds. ► Temperature of structural transformations is evidenced as a function of Ba content. ► Correlation between thermodynamic, electrical and structural data is investigated. ► The results are discussed based on the properties-defect structure relationship.