Crystal structure of bis(isothiocyanato)[2,6-diacetylpyridine bis(4-hydroxybenzoylhydrazone)]Fe(III) Chloride bis(dimethylformamide) solvate
The crystal structure of title compound (Fe[(C 25 H 21 N 7 O 4 S 2 )] · 4(C 3 NOH 7 ), where C 3 NOH 7 is dimethylformamide, DMF) was determined by the X-ray diffraction method. This compound crystallizes in the monoclinic C2/c space group, Z = 4. Unit cell parameters are: a = 13.6080(5), b = 17.637...
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| Veröffentlicht in: | Crystallography reports 2013-01, Vol.58 (1), p.98-101 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The crystal structure of title compound (Fe[(C
25
H
21
N
7
O
4
S
2
)] · 4(C
3
NOH
7
), where C
3
NOH
7
is dimethylformamide, DMF) was determined by the X-ray diffraction method. This compound crystallizes in the monoclinic C2/c space group,
Z
= 4. Unit cell parameters are:
a
= 13.6080(5),
b
= 17.6375(7),
c
= 19.5571(6) Å, β = 108.753(2)°. The N-H...O and O-H...O interactions stabilize the molecules in the lattice. The structure contains also the solvent dimethylformamide molecules, which are connected with intermoleculer hydrogen bond. The O atoms of DMF molecules take place as acceptor atoms. |
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| ISSN: | 1063-7745 1562-689X |
| DOI: | 10.1134/S1063774513010173 |