Solid and liquid spectroscopic analysis (SALSA)-a soft x-ray spectroscopy endstation with a novel flow-through liquid cell

We present a novel synchrotron endstation with a flow-through liquid cell designed to study the electronic structure of liquids using soft x-ray spectroscopies. In this cell, the liquid under study is separated from the vacuum by a thin window membrane, such that the sample liquid can be investigate...

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Veröffentlicht in:Review of scientific instruments 2009-12, Vol.80 (12), p.123102-123102-6
Hauptverfasser: Blum, M., Weinhardt, L., Fuchs, O., Bär, M., Zhang, Y., Weigand, M., Krause, S., Pookpanratana, S., Hofmann, T., Yang, W., Denlinger, J. D., Umbach, E., Heske, C.
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Sprache:eng
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Zusammenfassung:We present a novel synchrotron endstation with a flow-through liquid cell designed to study the electronic structure of liquids using soft x-ray spectroscopies. In this cell, the liquid under study is separated from the vacuum by a thin window membrane, such that the sample liquid can be investigated at ambient pressure. The temperature of the probing volume can be varied in a broad range and with a fast temperature response. The optimized design of the cell significantly reduces the amount of required sample liquid and allows the use of different window membrane types necessary to cover a broad energy range. The liquid cell is integrated into the s olid a nd l iquid s pectroscopic a nalysis (SALSA) endstation that includes a high-resolution, high-transmission x-ray spectrometer and a state-of-the-art electron analyzer. The modular design of SALSA also allows the measurement of solid-state samples. The capabilities of the liquid cell and the x-ray spectrometer are demonstrated using a resonant inelastic x-ray scattering map of a 25 wt% NaOD solution.
ISSN:0034-6748
1089-7623
DOI:10.1063/1.3257926