Engineering In Situ Catalytic Cleaning Membrane Via Prebiotic‐Chemistry‐Inspired Mineralization

Pressure‐driven membrane separation promises a sustainable energy‐water nexus but is hindered by ubiquitous fouling. Natural systems evolved from prebiotic chemistry offer a glimpse of creative solutions. Herein, a prebiotic‐chemistry‐inspired aminomalononitrile (AMN)/Mn2+‐mediated mineralization method is reported for universally engineering a superhydrophilic hierarchical MnO2 nanocoating to endow hydrophobic polymeric membranes with exceptional catalytic cleaning ability. Green hydrogen peroxide catalytically triggered in‐situ cleaning of the mineralized membrane and enabled operando flux recovery to reach 99.8%. The mineralized membrane exhibited a 9‐fold higher recovery compared to the unmineralized membrane, which is attributed to active catalytic antifouling coupled with passive hydration antifouling. Electron density differences derived from the precursor interaction during mediated mineralization unveiled an electron‐rich bell‐like structure with an inner electron‐deficient Mn core. This work paves the way to construct multifunctional engineered materials for energy‐efficient water treatment as well as for diverse promising applications in catalysis, solar steam generation, biomedicine, and beyond. A prebiotic‐chemistry‐inspired aminomalononitrile‐mediated mineralization strategy is developed for aqueous dip‐coating of catalytic nanomaterials onto the hydrophobic polymeric membrane at room temperature. The biomimetic mineralized superhydrophilic membrane enables the operando flux recovery beyond 99.8% and a ninefold higher flux recovery compared to the control one, attributed to active catalytic antifouling coupled with passive hydration antifouling.