Study of lithium borosilicotitanate glasses with LiCl

Study of lithium borosilicotitanate glasses with LiCl

The effect of LiCl addition on the properties of Li{sub 2}O: B{sub 2}O{sub 3}: SiO{sub 2}: TiO{sub 2} glasses has been studied. It has been observed that the ionic conductivity increases by about half an order with LiCl addition. The decrease in glass transition temperature T{sub g} and increase in...

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Bibliographische Detailangaben
Hauptverfasser: Deshpande, A. V., Paighan, N. S.
Format: Tagungsbericht
Sprache:eng
Schlagworte:
BORON OXIDES
BOROSILICATE GLASS
CHLORINE IONS
CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
CORRELATIONS
DENSITY
INTERSTITIALS
IONIC CONDUCTIVITY
LITHIUM CHLORIDES
LITHIUM OXIDES
MATERIALS SCIENCE
SILICON OXIDES
TITANIUM OXIDES
TRANSITION TEMPERATURE
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Zusammenfassung:The effect of LiCl addition on the properties of Li{sub 2}O: B{sub 2}O{sub 3}: SiO{sub 2}: TiO{sub 2} glasses has been studied. It has been observed that the ionic conductivity increases by about half an order with LiCl addition. The decrease in glass transition temperature T{sub g} and increase in the molar volume with LiCl addition have good correlation with conductivity results. The observed increase in density of glasses has been explained on the basis of heavier Cl{sup -} ion which is accommodated in the interstices in the glass network.
ISSN:0094-243X
1551-7616
DOI:10.1063/1.4710146