Properties of hollow molecules probed by single-photon double ionization

The formation of hollow molecules (with a completely empty K shell in one constituent atom) through single-photon core double ionization has been demonstrated using a sensitive magnetic bottle experimental technique combined with synchrotron radiation. Detailed properties are presented such as the s...

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Veröffentlicht in:Physical review letters 2011-02, Vol.106 (6), p.063003-063003, Article 063003
Hauptverfasser: Lablanquie, P, Penent, F, Palaudoux, J, Andric, L, Selles, P, Carniato, S, Bučar, K, Zitnik, M, Huttula, M, Eland, J H D, Shigemasa, E, Soejima, K, Hikosaka, Y, Suzuki, I H, Nakano, M, Ito, K
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Sprache:eng
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Zusammenfassung:The formation of hollow molecules (with a completely empty K shell in one constituent atom) through single-photon core double ionization has been demonstrated using a sensitive magnetic bottle experimental technique combined with synchrotron radiation. Detailed properties are presented such as the spectroscopy, formation, and decay dynamics of the N(2)(2+) K(-2) main and satellite states and the strong chemical shifts of double K holes on an oxygen atom in CO, CO2, and O2 molecules.
ISSN:0031-9007
1079-7114
DOI:10.1103/physrevlett.106.063003