Dye-coated europium monosulfide

Nanoparticles of EuS were synthesized using europium dithiocarbamate complexes. The resulting nanoparticles were coated with the dye, 1-pyrene carboxylic acid and the resulting material was characterized using X-ray powder diffraction, TEM, and UV-visible spectroscopy. Fluorescence spectroscopy was...

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Veröffentlicht in:Journal of solid state chemistry 2011-05, Vol.184 (5), p.1324-1327
Hauptverfasser: Kar, Srotoswini, Dollahon, Norman R., Stoll, Sarah L.
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container_title Journal of solid state chemistry
container_volume 184
creator Kar, Srotoswini
Dollahon, Norman R.
Stoll, Sarah L.
description Nanoparticles of EuS were synthesized using europium dithiocarbamate complexes. The resulting nanoparticles were coated with the dye, 1-pyrene carboxylic acid and the resulting material was characterized using X-ray powder diffraction, TEM, and UV-visible spectroscopy. Fluorescence spectroscopy was used to determine the relative energy of the conduction band edge to the excited state energy of the dye. Dye sensitized magnetic semiconductor materials were prepared by synthesizing EuS nanoparticles using single source precursors and coating with the dye, 1-pyrene carboxylic acid. [Display omitted] ► Synthesized EuS nanoparticles, 11±2.4 nm characterized using XRD, TEM, and UV–vis. spect. ► Grafted a dye to the surface and characterized the product using XRD, FTIR, UV–vis., and TEM. ► Studied the photophysical properties using fluorescence spectroscopy. ► Determined the relative dye excited state to the conduction band of the semiconductor.
doi_str_mv 10.1016/j.jssc.2011.03.028
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subjects 1-pyrene carboxylic acid
AROMATICS
AZAARENES
CARBAMATES
CARBONIC ACID DERIVATIVES
CARBOXYLIC ACID SALTS
CARBOXYLIC ACIDS
CHALCOGENIDES
COHERENT SCATTERING
COMPLEXES
COMPUTERIZED TOMOGRAPHY
CONDENSED AROMATICS
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Cross-disciplinary physics: materials science
rheology
DIAGNOSTIC TECHNIQUES
DIFFRACTION
Dye sensitized semiconductor
Dyes
ELECTRON MICROSCOPY
EMISSION COMPUTED TOMOGRAPHY
EMISSION SPECTROSCOPY
Energy use
Europium
EUROPIUM COMPLEXES
EUROPIUM COMPOUNDS
Europium dithiocarbamate
Europium monosulfide
EUROPIUM SULFIDES
Exact sciences and technology
Excitation spectra
FLUORESCENCE SPECTROSCOPY
HETEROCYCLIC COMPOUNDS
HYDROCARBONS
INFRARED SPECTRA
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
MAGNETIC SEMICONDUCTORS
MATERIALS
Materials science
Methods of nanofabrication
MICROSCOPY
Nanoparticles
Nanoscale materials and structures: fabrication and characterization
NANOSTRUCTURES
Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
Other topics in nanoscale materials and structures
PHENANTHROLINES
Photoluminescence
Physics
PYRENE
RARE EARTH COMPLEXES
RARE EARTH COMPOUNDS
SCATTERING
SEMICONDUCTOR MATERIALS
SINGLE PHOTON EMISSION COMPUTED TOMOGRAPHY
SPECTRA
SPECTROSCOPY
SULFIDES
SULFUR COMPOUNDS
TOMOGRAPHY
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION
title Dye-coated europium monosulfide
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