Dye-coated europium monosulfide

Nanoparticles of EuS were synthesized using europium dithiocarbamate complexes. The resulting nanoparticles were coated with the dye, 1-pyrene carboxylic acid and the resulting material was characterized using X-ray powder diffraction, TEM, and UV-visible spectroscopy. Fluorescence spectroscopy was...

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Veröffentlicht in:Journal of solid state chemistry 2011-05, Vol.184 (5), p.1324-1327
Hauptverfasser: Kar, Srotoswini, Dollahon, Norman R., Stoll, Sarah L.
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Sprache:eng
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Zusammenfassung:Nanoparticles of EuS were synthesized using europium dithiocarbamate complexes. The resulting nanoparticles were coated with the dye, 1-pyrene carboxylic acid and the resulting material was characterized using X-ray powder diffraction, TEM, and UV-visible spectroscopy. Fluorescence spectroscopy was used to determine the relative energy of the conduction band edge to the excited state energy of the dye. Dye sensitized magnetic semiconductor materials were prepared by synthesizing EuS nanoparticles using single source precursors and coating with the dye, 1-pyrene carboxylic acid. [Display omitted] ► Synthesized EuS nanoparticles, 11±2.4 nm characterized using XRD, TEM, and UV–vis. spect. ► Grafted a dye to the surface and characterized the product using XRD, FTIR, UV–vis., and TEM. ► Studied the photophysical properties using fluorescence spectroscopy. ► Determined the relative dye excited state to the conduction band of the semiconductor.
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2011.03.028