Ultrasmall iron nanoparticles: Effect of size reduction on anisotropy and magnetization

Stable iron nanoparticles have been synthesised by the decomposition of {Fe(N[Si(CH3)3]2)2}2 under dihydrogen pressure. Those conditions lead to a system of monodisperse and metallic nanoparticles which diameter is less than 2nm and stabilized by HN[Si(CH3)3]2. The magnetization is found to be MS=1.92μB∕at., i.e., 10% lower than the bulk value. The Mössbauer spectrum is fitted by two contributions of metallic iron. The magnetic anisotropy energy constant increases up to 5.2×105J∕m3, i.e., ten times the bulk one.