Electromagnetic transport properties and magnetoresistance of La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3}-Ag composites prepared by electroless process

A series of bulk polycrystalline La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3} (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (...

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Veröffentlicht in:Journal of solid state chemistry 2008-09, Vol.181 (9)
Hauptverfasser: Xiong, C.S., Cui, Y.F., Xiong, Y.H., Pi, H.L., Bao, X.C., Huang, Q.P., Zeng, Y., Wei, F.F., Zheng, C.F., Zhu, J.
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container_issue 9
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container_title Journal of solid state chemistry
container_volume 181
creator Xiong, C.S.
Cui, Y.F.
Xiong, Y.H.
Pi, H.L.
Bao, X.C.
Huang, Q.P.
Zeng, Y.
Wei, F.F.
Zheng, C.F.
Zhu, J.
description A series of bulk polycrystalline La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3} (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (SEM), and electromagnetic transport properties, we can see that Ag-added segregated at the surfaces or interfaces of LCSMO grains. The metal-insulator transition temperature (T{sub P}) and Curie temperature (T{sub c}) were almost unchanged but {rho} decreased with increasing plating time. We also observed Ag-added can significantly enhance the magnetoresistance (MR) near T{sub P} under a low applied field (3000 Oe) and the room temperature MR reached to 35% under 20 kOe, which is encouraging for practical applications. We can suggest that improved grain boundary effect by Ag-added is responsible for the enhancement. - Graphical abstract: Magnetic field dependence of the MR for the composites at 298 K. The inset is the different silver-plating time dependence of the variation of MR at 2 T.
doi_str_mv 10.1016/j.jssc.2008.04.041
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subjects COMPOSITE MATERIALS
CURIE POINT
GRAIN BOUNDARIES
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
INTERFACES
LANTHANUM COMPOUNDS
MAGNETIC FIELDS
MAGNETORESISTANCE
MANGANESE COMPOUNDS
OXIDES
PLATING
POLYCRYSTALS
SCANNING ELECTRON MICROSCOPY
SILVER
STRONTIUM COMPOUNDS
SURFACES
TEMPERATURE RANGE 0273-0400 K
TIME DEPENDENCE
X-RAY DIFFRACTION
title Electromagnetic transport properties and magnetoresistance of La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3}-Ag composites prepared by electroless process
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