Electromagnetic transport properties and magnetoresistance of La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3}-Ag composites prepared by electroless process
A series of bulk polycrystalline La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3} (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (...
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creator | Xiong, C.S. Cui, Y.F. Xiong, Y.H. Pi, H.L. Bao, X.C. Huang, Q.P. Zeng, Y. Wei, F.F. Zheng, C.F. Zhu, J. |
description | A series of bulk polycrystalline La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3} (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (SEM), and electromagnetic transport properties, we can see that Ag-added segregated at the surfaces or interfaces of LCSMO grains. The metal-insulator transition temperature (T{sub P}) and Curie temperature (T{sub c}) were almost unchanged but {rho} decreased with increasing plating time. We also observed Ag-added can significantly enhance the magnetoresistance (MR) near T{sub P} under a low applied field (3000 Oe) and the room temperature MR reached to 35% under 20 kOe, which is encouraging for practical applications. We can suggest that improved grain boundary effect by Ag-added is responsible for the enhancement. - Graphical abstract: Magnetic field dependence of the MR for the composites at 298 K. The inset is the different silver-plating time dependence of the variation of MR at 2 T. |
doi_str_mv | 10.1016/j.jssc.2008.04.041 |
format | Article |
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According to the results of X-ray diffraction (XRD), scanning electron microscopy (SEM), and electromagnetic transport properties, we can see that Ag-added segregated at the surfaces or interfaces of LCSMO grains. The metal-insulator transition temperature (T{sub P}) and Curie temperature (T{sub c}) were almost unchanged but {rho} decreased with increasing plating time. We also observed Ag-added can significantly enhance the magnetoresistance (MR) near T{sub P} under a low applied field (3000 Oe) and the room temperature MR reached to 35% under 20 kOe, which is encouraging for practical applications. We can suggest that improved grain boundary effect by Ag-added is responsible for the enhancement. - Graphical abstract: Magnetic field dependence of the MR for the composites at 298 K. 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According to the results of X-ray diffraction (XRD), scanning electron microscopy (SEM), and electromagnetic transport properties, we can see that Ag-added segregated at the surfaces or interfaces of LCSMO grains. The metal-insulator transition temperature (T{sub P}) and Curie temperature (T{sub c}) were almost unchanged but {rho} decreased with increasing plating time. We also observed Ag-added can significantly enhance the magnetoresistance (MR) near T{sub P} under a low applied field (3000 Oe) and the room temperature MR reached to 35% under 20 kOe, which is encouraging for practical applications. We can suggest that improved grain boundary effect by Ag-added is responsible for the enhancement. - Graphical abstract: Magnetic field dependence of the MR for the composites at 298 K. The inset is the different silver-plating time dependence of the variation of MR at 2 T.</description><subject>COMPOSITE MATERIALS</subject><subject>CURIE POINT</subject><subject>GRAIN BOUNDARIES</subject><subject>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</subject><subject>INTERFACES</subject><subject>LANTHANUM COMPOUNDS</subject><subject>MAGNETIC FIELDS</subject><subject>MAGNETORESISTANCE</subject><subject>MANGANESE COMPOUNDS</subject><subject>OXIDES</subject><subject>PLATING</subject><subject>POLYCRYSTALS</subject><subject>SCANNING ELECTRON MICROSCOPY</subject><subject>SILVER</subject><subject>STRONTIUM COMPOUNDS</subject><subject>SURFACES</subject><subject>TEMPERATURE RANGE 0273-0400 K</subject><subject>TIME DEPENDENCE</subject><subject>X-RAY DIFFRACTION</subject><issn>0022-4596</issn><issn>1095-726X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqNjk9LAzEQxYMouP75Ap4CnjfOpLvb7VFKxYPiQQ_eSppOa5ZtEjLxILKfw6_rautdePB-DO89RogrBIWAzU2nOmarNECroBqFR6JAmNXlVDevx6IA0Lqs6llzKs6YOwDEuq0K8bXoyeYUdmbrKTsrczKeY0hZxhQipeyIpfFruU-EROw4G29Jho18MJ_8vpKgpsP8D_XwnA6Iw6N_-uXJUN5upQ27GNjlcTImiibRWq4-JO1_6Il_7sGOfiFONqZnujz4ubi-W7zM78vA2S3Zjhv2zQbvx-ZSI-q20jD5X-oboMphpw</recordid><startdate>20080915</startdate><enddate>20080915</enddate><creator>Xiong, C.S.</creator><creator>Cui, Y.F.</creator><creator>Xiong, Y.H.</creator><creator>Pi, H.L.</creator><creator>Bao, X.C.</creator><creator>Huang, Q.P.</creator><creator>Zeng, Y.</creator><creator>Wei, F.F.</creator><creator>Zheng, C.F.</creator><creator>Zhu, J.</creator><scope>OTOTI</scope></search><sort><creationdate>20080915</creationdate><title>Electromagnetic transport properties and magnetoresistance of La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3}-Ag composites prepared by electroless process</title><author>Xiong, C.S. ; Cui, Y.F. ; Xiong, Y.H. ; Pi, H.L. ; Bao, X.C. ; Huang, Q.P. ; Zeng, Y. ; Wei, F.F. ; Zheng, C.F. ; Zhu, J.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-osti_scitechconnect_211284203</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2008</creationdate><topic>COMPOSITE MATERIALS</topic><topic>CURIE POINT</topic><topic>GRAIN BOUNDARIES</topic><topic>INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY</topic><topic>INTERFACES</topic><topic>LANTHANUM COMPOUNDS</topic><topic>MAGNETIC FIELDS</topic><topic>MAGNETORESISTANCE</topic><topic>MANGANESE COMPOUNDS</topic><topic>OXIDES</topic><topic>PLATING</topic><topic>POLYCRYSTALS</topic><topic>SCANNING ELECTRON MICROSCOPY</topic><topic>SILVER</topic><topic>STRONTIUM COMPOUNDS</topic><topic>SURFACES</topic><topic>TEMPERATURE RANGE 0273-0400 K</topic><topic>TIME DEPENDENCE</topic><topic>X-RAY DIFFRACTION</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xiong, C.S.</creatorcontrib><creatorcontrib>Cui, Y.F.</creatorcontrib><creatorcontrib>Xiong, Y.H.</creatorcontrib><creatorcontrib>Pi, H.L.</creatorcontrib><creatorcontrib>Bao, X.C.</creatorcontrib><creatorcontrib>Huang, Q.P.</creatorcontrib><creatorcontrib>Zeng, Y.</creatorcontrib><creatorcontrib>Wei, F.F.</creatorcontrib><creatorcontrib>Zheng, C.F.</creatorcontrib><creatorcontrib>Zhu, J.</creatorcontrib><collection>OSTI.GOV</collection><jtitle>Journal of solid state chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xiong, C.S.</au><au>Cui, Y.F.</au><au>Xiong, Y.H.</au><au>Pi, H.L.</au><au>Bao, X.C.</au><au>Huang, Q.P.</au><au>Zeng, Y.</au><au>Wei, F.F.</au><au>Zheng, C.F.</au><au>Zhu, J.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electromagnetic transport properties and magnetoresistance of La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3}-Ag composites prepared by electroless process</atitle><jtitle>Journal of solid state chemistry</jtitle><date>2008-09-15</date><risdate>2008</risdate><volume>181</volume><issue>9</issue><issn>0022-4596</issn><eissn>1095-726X</eissn><abstract>A series of bulk polycrystalline La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3} (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (SEM), and electromagnetic transport properties, we can see that Ag-added segregated at the surfaces or interfaces of LCSMO grains. The metal-insulator transition temperature (T{sub P}) and Curie temperature (T{sub c}) were almost unchanged but {rho} decreased with increasing plating time. We also observed Ag-added can significantly enhance the magnetoresistance (MR) near T{sub P} under a low applied field (3000 Oe) and the room temperature MR reached to 35% under 20 kOe, which is encouraging for practical applications. We can suggest that improved grain boundary effect by Ag-added is responsible for the enhancement. - Graphical abstract: Magnetic field dependence of the MR for the composites at 298 K. The inset is the different silver-plating time dependence of the variation of MR at 2 T.</abstract><cop>United States</cop><doi>10.1016/j.jssc.2008.04.041</doi></addata></record> |
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subjects | COMPOSITE MATERIALS CURIE POINT GRAIN BOUNDARIES INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY INTERFACES LANTHANUM COMPOUNDS MAGNETIC FIELDS MAGNETORESISTANCE MANGANESE COMPOUNDS OXIDES PLATING POLYCRYSTALS SCANNING ELECTRON MICROSCOPY SILVER STRONTIUM COMPOUNDS SURFACES TEMPERATURE RANGE 0273-0400 K TIME DEPENDENCE X-RAY DIFFRACTION |
title | Electromagnetic transport properties and magnetoresistance of La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3}-Ag composites prepared by electroless process |
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