Electromagnetic transport properties and magnetoresistance of La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3}-Ag composites prepared by electroless process
A series of bulk polycrystalline La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3} (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (...
Gespeichert in:
Veröffentlicht in: | Journal of solid state chemistry 2008-09, Vol.181 (9) |
---|---|
Hauptverfasser: | , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | A series of bulk polycrystalline La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3} (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (SEM), and electromagnetic transport properties, we can see that Ag-added segregated at the surfaces or interfaces of LCSMO grains. The metal-insulator transition temperature (T{sub P}) and Curie temperature (T{sub c}) were almost unchanged but {rho} decreased with increasing plating time. We also observed Ag-added can significantly enhance the magnetoresistance (MR) near T{sub P} under a low applied field (3000 Oe) and the room temperature MR reached to 35% under 20 kOe, which is encouraging for practical applications. We can suggest that improved grain boundary effect by Ag-added is responsible for the enhancement. - Graphical abstract: Magnetic field dependence of the MR for the composites at 298 K. The inset is the different silver-plating time dependence of the variation of MR at 2 T. |
---|---|
ISSN: | 0022-4596 1095-726X |
DOI: | 10.1016/j.jssc.2008.04.041 |