Electromagnetic transport properties and magnetoresistance of La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3}-Ag composites prepared by electroless process

A series of bulk polycrystalline La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3} (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of solid state chemistry 2008-09, Vol.181 (9)
Hauptverfasser: Xiong, C.S., Cui, Y.F., Xiong, Y.H., Pi, H.L., Bao, X.C., Huang, Q.P., Zeng, Y., Wei, F.F., Zheng, C.F., Zhu, J.
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A series of bulk polycrystalline La{sub 0.7}Ca{sub 0.2}Sr{sub 0.1}MnO{sub 3} (LCSMO)-Ag composites were prepared by electroless plating process and several kinds of physical properties have been studied systemically. According to the results of X-ray diffraction (XRD), scanning electron microscopy (SEM), and electromagnetic transport properties, we can see that Ag-added segregated at the surfaces or interfaces of LCSMO grains. The metal-insulator transition temperature (T{sub P}) and Curie temperature (T{sub c}) were almost unchanged but {rho} decreased with increasing plating time. We also observed Ag-added can significantly enhance the magnetoresistance (MR) near T{sub P} under a low applied field (3000 Oe) and the room temperature MR reached to 35% under 20 kOe, which is encouraging for practical applications. We can suggest that improved grain boundary effect by Ag-added is responsible for the enhancement. - Graphical abstract: Magnetic field dependence of the MR for the composites at 298 K. The inset is the different silver-plating time dependence of the variation of MR at 2 T.
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2008.04.041