Dichroism and birefringence of natural violet diamond crystals

Investigation of the optical properties of natural violet diamonds from the Yakutian kimberlites is performed. A red shift of the absorption edge is revealed in the absorption spectra of these crystals. This shift is indicative of the presence of a high concentration of nitrogen in the diamonds stud...

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Veröffentlicht in:Crystallography reports 2006-05, Vol.51 (3), p.465-471
Hauptverfasser: Konstantinova, A. F., Titkov, S. V., Imangazieva, K. B., Evdishchenko, E. A., Sergeev, A. M., Zudin, N. G., Orekhova, V. P.
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Sprache:eng
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Zusammenfassung:Investigation of the optical properties of natural violet diamonds from the Yakutian kimberlites is performed. A red shift of the absorption edge is revealed in the absorption spectra of these crystals. This shift is indicative of the presence of a high concentration of nitrogen in the diamonds studied. Along with the strong band at 0.550 {mu}m, weaker bands at 0.390, 0.456 and 0.496 {mu}m are revealed. It is shown that violet diamond crystals have birefringence and dichroism of about 10{sup -5} and 10{sup -6}, respectively. When a light beam propagates perpendicularly to colored lamellas, the dichroism is much larger and the birefringence is smaller than in the case where the beam direction is parallel to lamellas.
ISSN:1063-7745
1562-689X
DOI:10.1134/S1063774506030151