Peculiarities of changes of some physicomechanical characteristics of monoisotopes {sup 10}B, {sup 11}B and natural {beta}-boron

Real structure and some physicomechanical characteristics of the samples of natural beta-rhombohedral boron B as well as of its {sup 10}B and {sup 11}B monoisotopes have been studied. It was shown that the influence of {sup 10}B and {sup 11}B isotopes on physicomechanical properties of boron had a d...

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Veröffentlicht in:Journal of solid state chemistry 2006-09, Vol.179 (9)
Hauptverfasser: Gabunia, D., Tsagareishvili, O., Lezhava, D., Gabunia, L., Antadze, M., Darsavelidze, G., Tanaka, T.
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Sprache:eng
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Zusammenfassung:Real structure and some physicomechanical characteristics of the samples of natural beta-rhombohedral boron B as well as of its {sup 10}B and {sup 11}B monoisotopes have been studied. It was shown that the influence of {sup 10}B and {sup 11}B isotopes on physicomechanical properties of boron had a different character. In particular, the samples enriched with {sup 11}B had high values of microhardness, shear modulus (SM) and elastic limit if compared to those of boron, while the samples enriched with {sup 10}B monoisotopes were characterized with high values of thermal expansion coefficient (TEC) and thermal conductivity; lattice parameters a and c increased by the sequence: {sup 11}B, B, {sup 10}B. It was established that TEC, thermal conductivity, microhardness, SM and shear elastic limit increased in all samples at annealing for 5 h at 1500 deg. C regardless of isotope content. - Graphical abstract: Temperature dependence of the SM in the samples of natural boron B, {sup 10}B and {sup 11}B monoisotopes.
ISSN:0022-4596
1095-726X
DOI:10.1016/j.jssc.2006.05.024