Intercalation of cyclic ketones into vanadyl phosphate

Intercalation compounds of vanadyl phosphate with cyclic ketones (cyclopentanone, cyclohexanone, 4-methylcyclohexanone, and 1,4-cyclohexanedione) were prepared from corresponding propanol or ethanol intercalates by a molecular exchange. The intercalates prepared were characterized using powder X-ray diffraction and thermogravimetric analysis. The intercalates are stable in dry environment and decompose slowly in humid air. Infrared and Raman spectra indicate that carbonyl oxygens of the guest molecules are coordinated to the vanadium atoms of the host layers. The local structure and interactions in the cyclopentanone intercalate have been suggested on the basis of quantum chemical calculations. Intercalation compounds of vanadyl phosphate with cyclic ketones were prepared and characterized using powder X-ray diffraction, thermogravimetric analysis and vibrational spectra. On the basis of quantum chemical calculations the arrangement of cyclopentanone molecules in the interlayer space of vanadyl phosphate has been suggested.